C. Proa-Coronado, J.A. Balderas-López, Y. Sánchez-Fuentes, L.A. Linares-Duarte, E. Hernández-Sánchez
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引用次数: 0
Abstract
In this work Photopyroelectric Techniques for thermal and optical characterization are introduced for measuring thermal diffusivity and optical absorption coefficient of colloidal suspensions of SiO2. Thermal diffusivity and Optical absorption coefficients at 904 nm, 940 nm, 980 nm and 1550 nm were measured for spherical SiO2 colloidal suspensions of 61 and 673 nm average size, in a range of 1 mg/mL to 26 mg/mL. It was found a linear increment of this optical property with SiO2 nano-spheres concentration, which was not possible to obtain by means of absorbance measurements with conventional UV-Vis spectroscopy; in relation with thermal diffusivity it was found a slightly increment of this thermal property with increasing concentration, however this increment was not as large as the one reported for similar samples but using experimental techniques involving the optical properties of the samples. The direct measurement of optical absorption coefficients of colloidal suspensions allowed the knowledge of their absorptivity at the selected wavelengths. The presented methodology could be useful for measuring this optical property for colloidal suspensions in general at other wavelengths and as a function of other variables of interest, such as size particle.
期刊介绍:
Thermochimica Acta publishes original research contributions covering all aspects of thermoanalytical and calorimetric methods and their application to experimental chemistry, physics, biology and engineering. The journal aims to span the whole range from fundamental research to practical application.
The journal focuses on the research that advances physical and analytical science of thermal phenomena. Therefore, the manuscripts are expected to provide important insights into the thermal phenomena studied or to propose significant improvements of analytical or computational techniques employed in thermal studies. Manuscripts that report the results of routine thermal measurements are not suitable for publication in Thermochimica Acta.
The journal particularly welcomes papers from newly emerging areas as well as from the traditional strength areas:
- New and improved instrumentation and methods
- Thermal properties and behavior of materials
- Kinetics of thermally stimulated processes