Effect of the Al/Si ratio on intumescent Na-based geopolymer

IF 3.4 3区 工程技术 Q2 ENGINEERING, CIVIL
Qi Yang , Catherine A. Davy , Johan Sarazin , Serge Bourbigot , Gaëlle Fontaine
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引用次数: 0

Abstract

This research investigates the fire resistance properties of alkali activated Na-based geopolymers (GP), used as steel protective coatings. The effect of different Al/Si molar ratios (0–0.54) is evaluated fire test. When coated on a steel plate, GP having the smaller Al/Si ratio exhibits an intumescent behavior with the highest expansion. When Al/Si = 0, the temperature at the backside of the steel plate is 313 °C which is decreased by 347 °C compared to an uncoated steel plate (660 °C). After fire testing, the GP physico-chemical properties are characterized with optical microscopy, Electron probe micro-analysis, dynamic mechanical analysis. According to stiffness test results, when the temperature approaches 100 °C, the GP with a given Al/Si ratio (different from zero) softens and expands (intumescence). The greater the Al/Si ratio in the GP, the more rigid the structure; this phenomenon limits expansion, and hence, lowers the fire protection.

铝/硅比对膨胀型 Na 基土工聚合物的影响
本研究调查了用作钢铁保护涂层的碱活化 Na 基土工聚合物 (GP) 的耐火性能。在火灾试验中评估了不同铝/硅摩尔比(0-0.54)的影响。在钢板上涂覆时,铝/硅比率较小的 GP 表现出膨胀性最高的膨胀行为。当 Al/Si = 0 时,钢板背面的温度为 313 °C,与未涂层钢板(660 °C)相比降低了 347 °C。火灾测试后,使用光学显微镜、电子探针显微分析和动态机械分析对 GP 的物理化学特性进行了表征。根据刚度测试结果,当温度接近 100 ℃ 时,特定铝/硅比(不同于零)的 GP 会变软并膨胀(膨胀)。GP 中的铝/硅比越大,结构就越坚硬;这种现象限制了膨胀,从而降低了防火性能。
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来源期刊
Fire Safety Journal
Fire Safety Journal 工程技术-材料科学:综合
CiteScore
5.70
自引率
9.70%
发文量
153
审稿时长
60 days
期刊介绍: Fire Safety Journal is the leading publication dealing with all aspects of fire safety engineering. Its scope is purposefully wide, as it is deemed important to encourage papers from all sources within this multidisciplinary subject, thus providing a forum for its further development as a distinct engineering discipline. This is an essential step towards gaining a status equal to that enjoyed by the other engineering disciplines.
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