Tingting Xiong, Changjun Zou, Huihui Wang, Yujie Hu, Yan Xiong
{"title":"Cucurbit[7]uril-Modified Nano SiO<sub>2</sub> for Efficient Separation of Crude Oil Emulsions: Properties and Demulsification Mechanism.","authors":"Tingting Xiong, Changjun Zou, Huihui Wang, Yujie Hu, Yan Xiong","doi":"10.1021/acs.langmuir.4c01583","DOIUrl":null,"url":null,"abstract":"<p><p>Demulsification of crude oil emulsion is an obvious problem in the whole of petroleum engineering, which needs to be dealt with urgently. In this paper, a supramolecular material Cucurbit[7]uril-SiO<sub>2</sub> (CB-SiO<sub>2</sub>) synthesized with excellent demulsification efficiency (DE) on O/W emulsion was synthesized by a simple thermal synthesis method. The microscopic morphology and structure were investigated through modern characterization techniques. Furthermore, its stability, dynamic interfacial tension (IFT), and wettability (three-phase contact angle (CA)) were systematically investigated, and the demulsification efficiency of different conditions on crude oil emulsion was also investigated. Reassuringly, these results showed that when the temperature was 70 °C, the demulsification dosage was close to 600 mg/L and remained unchanged for 90 min; the demulsification efficiency is 2.2 times compared with the unmodified material, up to 93.63%. In addition, a plausible demulsification mechanism was proposed, which is that CB-SiO<sub>2</sub> can adsorb and disrupt the oil-water interface, leading to oil-water separation and promoting demulsification. It is a promising demulsification material for the oil industry demulsification.</p>","PeriodicalId":50,"journal":{"name":"Langmuir","volume":null,"pages":null},"PeriodicalIF":3.7000,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Langmuir","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.langmuir.4c01583","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/7/11 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Demulsification of crude oil emulsion is an obvious problem in the whole of petroleum engineering, which needs to be dealt with urgently. In this paper, a supramolecular material Cucurbit[7]uril-SiO2 (CB-SiO2) synthesized with excellent demulsification efficiency (DE) on O/W emulsion was synthesized by a simple thermal synthesis method. The microscopic morphology and structure were investigated through modern characterization techniques. Furthermore, its stability, dynamic interfacial tension (IFT), and wettability (three-phase contact angle (CA)) were systematically investigated, and the demulsification efficiency of different conditions on crude oil emulsion was also investigated. Reassuringly, these results showed that when the temperature was 70 °C, the demulsification dosage was close to 600 mg/L and remained unchanged for 90 min; the demulsification efficiency is 2.2 times compared with the unmodified material, up to 93.63%. In addition, a plausible demulsification mechanism was proposed, which is that CB-SiO2 can adsorb and disrupt the oil-water interface, leading to oil-water separation and promoting demulsification. It is a promising demulsification material for the oil industry demulsification.
期刊介绍:
Langmuir is an interdisciplinary journal publishing articles in the following subject categories:
Colloids: surfactants and self-assembly, dispersions, emulsions, foams
Interfaces: adsorption, reactions, films, forces
Biological Interfaces: biocolloids, biomolecular and biomimetic materials
Materials: nano- and mesostructured materials, polymers, gels, liquid crystals
Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry
Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals
However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do?
Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*.
This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).