Aynur Manzak, Özlem Demirbaş, Yasemin Yıldız, Murat Teker
{"title":"Adsorption and transport of acid dye through polymer inclusion membrane with Aliquat 336 and TBP","authors":"Aynur Manzak, Özlem Demirbaş, Yasemin Yıldız, Murat Teker","doi":"10.1007/s11270-024-07318-8","DOIUrl":null,"url":null,"abstract":"<p>Colour is typically the initial pollutant identified in wastewater. Membrane separation represents a novel approach to separation processes, with expectations of supplanting many traditional separation systems. The aim of this study is to investigate polymer inclusion membranes (PIMs) consisting of tri octyl methyl ammonium chloride as the carrier, tributylphosphate as the modifier, poly-vinyl chloride as the base polymer and 2-Nitro phenyl pentyl ether as the plasticizer for removing an acid dye (Red Erionyl A-3G) from aqueous solution. The dye adsorption on the membrane surface and its transition to the stripping phase was achieved by placing the membrane between two glass cells. Changing the stripping solution ensured both adsorption on the membrane surface and the transfer of all the dye to the stripping stage. Using a mixture of 0.8 M salicylic acid and 0.8 M NaOH, along with stirring at 1000 rpm during the stripping phase, extraction efficiency reached 98% in the feed phase and 53% in the stripping phase. When 1 M NaOH solution was employed as the stripping solution, the membrane absorbed all the dye within 10 minutes, but there was no transition to the stripping phase. The membrane has a durability of 2 days.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\n","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water, Air, & Soil Pollution","FirstCategoryId":"6","ListUrlMain":"https://doi.org/10.1007/s11270-024-07318-8","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
Colour is typically the initial pollutant identified in wastewater. Membrane separation represents a novel approach to separation processes, with expectations of supplanting many traditional separation systems. The aim of this study is to investigate polymer inclusion membranes (PIMs) consisting of tri octyl methyl ammonium chloride as the carrier, tributylphosphate as the modifier, poly-vinyl chloride as the base polymer and 2-Nitro phenyl pentyl ether as the plasticizer for removing an acid dye (Red Erionyl A-3G) from aqueous solution. The dye adsorption on the membrane surface and its transition to the stripping phase was achieved by placing the membrane between two glass cells. Changing the stripping solution ensured both adsorption on the membrane surface and the transfer of all the dye to the stripping stage. Using a mixture of 0.8 M salicylic acid and 0.8 M NaOH, along with stirring at 1000 rpm during the stripping phase, extraction efficiency reached 98% in the feed phase and 53% in the stripping phase. When 1 M NaOH solution was employed as the stripping solution, the membrane absorbed all the dye within 10 minutes, but there was no transition to the stripping phase. The membrane has a durability of 2 days.
期刊介绍:
Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments.
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Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.