M. C. Maciel Arreola, J. A. Medina Cervantes, R. I. Yocupicio Gaxiola, A. Infantes Molina, R. Huirache-Acuña, S. Fuentes Moyado, G. Alonso Núñez
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Abstract
Nickel and cobalt sulfide-based catalysts supported on a silicon-pillared MFI zeolite were synthesized, characterized, and tested in the hydrodesulfurization reaction of dibenzothiophene. The metallic phases were incorporated by following the incipient wetness impregnation process, and different techniques were employed to determine the physicochemical properties of the obtained catalysts, such as X-ray diffraction, N2 adsorption–desorption at – 196 °C, Infrared Spectroscopy and High-Resolution Transmission Electron Microscopy. The catalytic performance in the hydrodesulfurization of dibenzothiophene showed that the NiW catalyst was the most active due to the redispersion of NiS on WS2 to form the active NiWS phase. Instead, the desired CoWS phase did not occur under the presence of cobalt, and therefore, the catalytic performance worsened.
期刊介绍：
MRS Communications is a full-color, high-impact journal focused on rapid publication of completed research with broad appeal to the materials community. MRS Communications offers a rapid but rigorous peer-review process and time to publication. Leveraging its access to the far-reaching technical expertise of MRS members and leading materials researchers from around the world, the journal boasts an experienced and highly respected board of principal editors and reviewers.
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