Solid Solutions of Pyridinium Halobismuthates

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI:10.1134/s003602362360288x

P. A. Buikin, A. S. Zhavoronkov, A. B. Ilyukhin, V. Yu. Kotov

引用次数: 0

Abstract

Solid solutions of pyridinium bromo-iodobismutates have been isolated from aqueous solutions and structurally characterized. The composition of the resulting solid solutions [HPy]BiX₄ and [HPy]₃Bi₂X₉ (X = Br, I) depends on the ratios of organic cation/bismuth and bromine/iodine in the initial solution. The existence of five polymorphic modifications in the system for compositions [HPy]BiX₄ has been shown. Two different polymorphs have been found for iodobismuthate [HPy]BiI₄.

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吡啶鎓卤铋盐固溶体

摘要从水溶液中分离出了溴碘铋酸吡啶鎓固溶体，并对其结构进行了表征。所得固溶体 [HPy]BiX4 和 [HPy]3Bi2X9 (X = Br, I) 的组成取决于初始溶液中有机阳离子/铋和溴/碘的比例。研究表明，[HPy]BiX4 成分在该体系中存在五种多晶形态。碘铋酸盐 [HPy]BiI4 发现了两种不同的多晶型。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

3.10

自引率

38.10%

发文量

237

审稿时长

3 months

期刊介绍： Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.