Extraction of Pb2+ Ions by Sodium Aluminosilicates Synthesized from Rice Straw

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
A. N. Kholomeydik, A. E. Panasenko
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引用次数: 0

Abstract

Samples of sodium aluminosilicates obtained by hydrolytic precipitation using rice straw of various types as silicon-containing feedstock were studied. The particle morphology was determined by scanning electron microscopy, the specific surface area was measured (362–470 m2/g), IR spectra were recorded, and the chemical and phase composition of the samples was determined. The sorption properties of the materials towards lead ions were studied, the sorption capacity was 199–550 mg/g. An organic component of the samples, formed simultaneously with aluminosilicate precipitation from rice straw hydrolysates, was detected, isolated, and studied by thermogravimetry and IR spectroscopy. The effect of the organic component on the sorption capacity of plant-derived aluminosilicates was investigated. The predominant sorption mechanisms were established. The used approach makes it possible to obtain aluminosilicates with a high sorption capacity, as well as safely dispose of rice straw.

Abstract Image

用稻草合成的铝硅酸钠萃取 Pb2+ 离子
摘要 研究了以各种类型的稻草为含硅原料,通过水解沉淀得到的铝硅酸钠样品。用扫描电子显微镜测定了颗粒形态,测量了比表面积(362-470 m2/g),记录了红外光谱,并确定了样品的化学成分和相组成。研究了材料对铅离子的吸附特性,其吸附容量为 199-550 毫克/克。样品中的有机成分是在水稻秸秆水解物沉淀出硅酸铝的同时形成的,对其进行了检测和分离,并通过热重法和红外光谱进行了研究。研究了有机成分对植物衍生铝硅酸盐吸附能力的影响。确定了主要的吸附机制。采用这种方法可以获得高吸附能力的铝硅酸盐,并能安全地处理稻草。
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来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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