Optical and Structural Properties of Cuprous Oxide Shell Coated Gold Nanoprisms

IF 2.7 4区 材料科学 Q3 CHEMISTRY, PHYSICAL
Dániel Zámbó, Dávid Kovács, András Deák
{"title":"Optical and Structural Properties of Cuprous Oxide Shell Coated Gold Nanoprisms","authors":"Dániel Zámbó, Dávid Kovács, András Deák","doi":"10.1002/ppsc.202400082","DOIUrl":null,"url":null,"abstract":"Cuprous oxide nanoparticles can be prepared with a great morphological control, and their composites with gold nanostructures are intensively studied owing to their catalytic performance. In this study, cuprous oxide shell growth on nanosized prism‐shaped gold nanoparticles is investigated, where the core‐particle morphology does not match the prototypical cubic or octahedral symmetry of the embedding cuprous oxide particle. It is shown that different shell morphology is obtained depending on the reducing agent used for the shell deposition. Strong reducing agent (hydrazine) leads to a multi‐slab‐like coating with smooth facets, while under milder conditions (hydroxylamine) a multi‐grain coating is obtained. Successful realization of time‐dependent spectroscopic and structural investigations indicate that in this latter case cuprous oxide shell growth is initiated site‐selectively, namely in the highly curved regions of the particle, with a higher growth rate around the tips of the nanoprisms. This is supported by correlative single‐nanoparticle spectroscopy/scanning electron microscopy measurements, that allow to establish the connection between the optical properties and the structure of these plasmonic/semiconductor core/shell nanoparticles.","PeriodicalId":19903,"journal":{"name":"Particle & Particle Systems Characterization","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Particle & Particle Systems Characterization","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/ppsc.202400082","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

Abstract

Cuprous oxide nanoparticles can be prepared with a great morphological control, and their composites with gold nanostructures are intensively studied owing to their catalytic performance. In this study, cuprous oxide shell growth on nanosized prism‐shaped gold nanoparticles is investigated, where the core‐particle morphology does not match the prototypical cubic or octahedral symmetry of the embedding cuprous oxide particle. It is shown that different shell morphology is obtained depending on the reducing agent used for the shell deposition. Strong reducing agent (hydrazine) leads to a multi‐slab‐like coating with smooth facets, while under milder conditions (hydroxylamine) a multi‐grain coating is obtained. Successful realization of time‐dependent spectroscopic and structural investigations indicate that in this latter case cuprous oxide shell growth is initiated site‐selectively, namely in the highly curved regions of the particle, with a higher growth rate around the tips of the nanoprisms. This is supported by correlative single‐nanoparticle spectroscopy/scanning electron microscopy measurements, that allow to establish the connection between the optical properties and the structure of these plasmonic/semiconductor core/shell nanoparticles.
氧化亚铜壳镀金纳米棱镜的光学和结构特性
氧化亚铜纳米粒子的制备具有很强的形态控制能力,由于其催化性能,人们对其与金纳米结构的复合材料进行了深入研究。本研究考察了氧化亚铜壳在纳米棱柱形金纳米粒子上的生长情况,其中核心粒子的形态与嵌入氧化亚铜粒子的原型立方或八面体对称性不匹配。研究表明,不同的外壳形态取决于用于外壳沉积的还原剂。强还原剂(肼)会产生具有光滑表面的多板状涂层,而在较温和的条件下(羟胺)则会产生多粒状涂层。成功实现的随时间变化的光谱和结构研究表明,在后一种情况下,氧化亚铜壳的生长是有部位选择性地开始的,即在颗粒的高度弯曲区域,纳米棱镜尖端周围的生长率较高。单个纳米粒子光谱学/扫描电子显微镜测量的相关性证实了这一点,从而建立了这些等离子/半导体核/壳纳米粒子的光学特性与结构之间的联系。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Particle & Particle Systems Characterization
Particle & Particle Systems Characterization 工程技术-材料科学:表征与测试
CiteScore
5.50
自引率
0.00%
发文量
114
审稿时长
3.0 months
期刊介绍: Particle & Particle Systems Characterization is an international, peer-reviewed, interdisciplinary journal focusing on all aspects of particle research. The journal joined the Advanced Materials family of journals in 2013. Particle has an impact factor of 4.194 (2018 Journal Impact Factor, Journal Citation Reports (Clarivate Analytics, 2019)). Topics covered include the synthesis, characterization, and application of particles in a variety of systems and devices. Particle covers nanotubes, fullerenes, micelles and alloy clusters, organic and inorganic materials, polymers, quantum dots, 2D materials, proteins, and other molecular biological systems. Particle Systems include those in biomedicine, catalysis, energy-storage materials, environmental science, micro/nano-electromechanical systems, micro/nano-fluidics, molecular electronics, photonics, sensing, and others. Characterization methods include microscopy, spectroscopy, electrochemical, diffraction, magnetic, and scattering techniques.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信