Self-limiting material growth triggered and tunable by force through piezocharge-induced mineralization†

Abstract

Controlling the growth of material is crucial in material processing for desired properties. Current approaches often involve sophisticated equipment for controlling precursors and monitoring material formation. Here we report a self-limiting material growth mechanism controlled by the experienced mechanical loading without the need for precise control over precursors or monitoring material growth. Material formation that reduces the driving force for growth is hypothesized to result in a saturation thickness that is dependent on the maximum driving force. Analytical relations based on the growth model are derived and verified using a piezoelectric substrate immersed in an electrolyte solution under fixed frequency cyclic loading to attract surrounding mineral ions to form mineral layers. Accumulating mineral layers decrease the driving force for further growth and the material eventually reaches a saturation thickness. This allows for loading force to control the saturation thickness of the self-limiting material growth. Experimental data supports the predicted exponential relations, offering guides to predict the saturation thickness and control the growth profile. The findings are envisioned to contribute to the fundamental understanding of the self-limiting material growth mechanism and could benefit a range of applications including coatings for orthopedic implants as well as marine surface and underwater vehicles.