Investigation into the Reaction of Hydrogen Iodide with a Chlorine Atom in the Atmosphere above the Sea

Pub Date : 2024-07-02 DOI:10.1134/s0001433824700178
I. K. Larin, G. B. Pronchev, E. M. Trofimova
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Abstract

Using the resonant fluorescence (RF) of chlorine atoms and iodine atoms, the rate constant of the reaction of a chlorine atom with hydrogen iodide at a temperature of 298 K is measured. The values of the reaction constants measured by both methods turns out to be quite similar. The role of this reaction in the chemistry of the troposphere above the surface of the oceans is discussed.

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关于海洋上空大气中碘化氢与氯原子反应的研究
摘要 利用氯原子和碘原子的共振荧光(RF),测量了氯原子在 298 K 温度下与碘化氢反应的速率常数。结果表明,两种方法测得的反应常数值非常相似。讨论了这一反应在海洋表面对流层化学中的作用。
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