Element-specific cluster growth on the two-dimensional metal–organic network

IF 1.5 4区 物理与天体物理 Q3 PHYSICS, APPLIED
Noriyuki Tsukahara, Ryuichi Arafune and Jun Yoshinobu
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引用次数: 0

Abstract

A porous two-dimensional metal–organic network (2D-MON) on a substrate captures deposited metal atoms and metal clusters growing in the pores of the 2D-MON. We found that the growth mechanisms of Ag, In, and Pd clusters in the 2D-MON synthesized from 1,3,5-tris(4-bromophenyl)benzene molecules on Ag(111) are different from each other, and the difference derives from the interaction of an adatom with the 2D-MON. Ag and Pd clusters grow from the 2D-MON since the interaction of Ag and Pd adatoms with the 2D-MON is attractive. In clusters grow inside of the pores of the 2D-MON since the interaction between an In adatom and the 2D-MON is repulsive. The growth process of metal clusters is determined by the element-specific behavior of metal adatoms in the pores, taking into account interactions with the 2D-MON.
二维金属有机网络上的元素特异性团簇生长
基底上的多孔二维金属有机网络(2D-MON)可以捕获沉积的金属原子和生长在 2D-MON 孔隙中的金属团簇。我们发现,在由 1,3,5-三(4-溴苯基)苯分子在 Ag(111) 上合成的二维金属有机网络中,Ag、In 和 Pd 团簇的生长机制各不相同,这种差异源于一个原子与二维金属有机网络的相互作用。由于 Ag 和 Pd 的原子与 2D-MON 的相互作用具有吸引力,因此 Ag 和 Pd 团簇从 2D-MON 生长出来。由于铟原子与二维金属膜之间的相互作用是排斥性的,因此铟原子簇会在二维金属膜的孔隙内生长。考虑到与 2D-MON 的相互作用,金属团簇的生长过程由金属原子在孔隙中的特定元素行为决定。
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来源期刊
Japanese Journal of Applied Physics
Japanese Journal of Applied Physics 物理-物理:应用
CiteScore
3.00
自引率
26.70%
发文量
818
审稿时长
3.5 months
期刊介绍: The Japanese Journal of Applied Physics (JJAP) is an international journal for the advancement and dissemination of knowledge in all fields of applied physics. JJAP is a sister journal of the Applied Physics Express (APEX) and is published by IOP Publishing Ltd on behalf of the Japan Society of Applied Physics (JSAP). JJAP publishes articles that significantly contribute to the advancements in the applications of physical principles as well as in the understanding of physics in view of particular applications in mind. Subjects covered by JJAP include the following fields: • Semiconductors, dielectrics, and organic materials • Photonics, quantum electronics, optics, and spectroscopy • Spintronics, superconductivity, and strongly correlated materials • Device physics including quantum information processing • Physics-based circuits and systems • Nanoscale science and technology • Crystal growth, surfaces, interfaces, thin films, and bulk materials • Plasmas, applied atomic and molecular physics, and applied nuclear physics • Device processing, fabrication and measurement technologies, and instrumentation • Cross-disciplinary areas such as bioelectronics/photonics, biosensing, environmental/energy technologies, and MEMS
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