Porous Cross-Linked Polymer PPBI@Mn Catalyzed the Selective Synthesis of Bisindolylmethane Derivatives

IF 2.3 4区化学 Q3 CHEMISTRY, PHYSICAL

Catalysis Letters Pub Date : 2024-07-02 DOI:10.1007/s10562-024-04760-5

Kai Zhang, Haiyan Zhu, Dawei Wang, Zheng-Chao Duan

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Abstract

The quest for highly active and efficient ligands in coordination polymer-based catalytic applications is paramount. The new porous cross-linked polymer manganese composites, which featured a benzimidazole-pyrimidine backbone, were designed, synthesized and fully characterized through several modern means. The resulting manganese composites revealed good catalytic activity in the selective synthesis of bisindolylmethane derivatives with high selectivity. Furthermore, the porous cross-linked polymer matrix composites displayed impressive recyclability, demonstrating their economic and environmental merits, with mechanistic studies shedding light on these transformative processes.

Graphical Abstract

The new porous cross-linked polymer manganese composites, which featured a benzimidazole-pyrimidine backbone. The resulting manganese composites revealed good catalytic activity in the selective synthesis of bisindolylmethane derivatives with high selectivity. Furthermore, the porous cross-linked polymer matrix composites displayed impressive recyclability, demonstrating their economic and environmental merits, with mechanistic studies shedding light on these transformative processes.

Abstract Image

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多孔交联聚合物 PPBI@Mn 催化双吲哚甲烷衍生物的选择性合成

在基于配位聚合物的催化应用中，寻找高活性和高效配体至关重要。通过多种现代手段，设计、合成并全面表征了以苯并咪唑-嘧啶为骨架的新型多孔交联聚合物锰复合材料。所制备的锰复合材料在选择性合成双吲哚甲烷衍生物方面具有良好的催化活性。此外，多孔交联聚合物基复合材料显示出令人印象深刻的可回收性，证明了其在经济和环境方面的优点，而机理研究则揭示了这些转化过程。所制备的锰复合材料在选择性合成双吲哚甲烷衍生物中具有良好的催化活性。此外，多孔交联聚合物基复合材料显示出令人印象深刻的可回收性，证明了其在经济和环境方面的优点，而机理研究则揭示了这些转化过程。

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来源期刊

Catalysis Letters 化学-物理化学

CiteScore

5.70

自引率

3.60%

发文量

327

审稿时长

1 months

期刊介绍： Catalysis Letters aim is the rapid publication of outstanding and high-impact original research articles in catalysis. The scope of the journal covers a broad range of topics in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis. The high-quality original research articles published in Catalysis Letters are subject to rigorous peer review. Accepted papers are published online first and subsequently in print issues. All contributions must include a graphical abstract. Manuscripts should be written in English and the responsibility lies with the authors to ensure that they are grammatically and linguistically correct. Authors for whom English is not the working language are encouraged to consider using a professional language-editing service before submitting their manuscripts.