Influence of Composition of Copolymers of Glycidyl Methacrylate and Alkyl Methacrylates on the Free Energy and Lyophilic Properties of the Coatings

IF 1 4区 化学 Q4 POLYMER SCIENCE
Yu. D. Grigor’eva, O. V. Kolyaganova, V. V. Klimov, E. V. Bryuzgin, A. V. Navrotskii, I. A. Novakov
{"title":"Influence of Composition of Copolymers of Glycidyl Methacrylate and Alkyl Methacrylates on the Free Energy and Lyophilic Properties of the Coatings","authors":"Yu. D. Grigor’eva,&nbsp;O. V. Kolyaganova,&nbsp;V. V. Klimov,&nbsp;E. V. Bryuzgin,&nbsp;A. V. Navrotskii,&nbsp;I. A. Novakov","doi":"10.1134/S1560090424600438","DOIUrl":null,"url":null,"abstract":"<p>The use of reactive copolymers of glycidyl methacrylate and alkyl methacrylates differing in the length of the alkyl substituent (С6–С18) has been suggested as alternative to fluorinated modifiers to efficiently reduce the surface free energy. The influence of the structure and composition of the copolymers on the surface free energy and the work of adhesion to polar and dispersive test liquids has been demonstrated. At a smooth surface, the polymer coatings based on the functional copolymers have exhibited low surface free energy (down to 19 mN/m) and to ensure the high-hydrophobic wetting state with contact angles up to 105°. The stability of the superhydrophobic state of the polymer coatings at the textured aluminum surface (the AMG2M grade) with initial wetting angles up to 168° has been investigated.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":"66 2","pages":"245 - 256"},"PeriodicalIF":1.0000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1560090424600438","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

Abstract

The use of reactive copolymers of glycidyl methacrylate and alkyl methacrylates differing in the length of the alkyl substituent (С6–С18) has been suggested as alternative to fluorinated modifiers to efficiently reduce the surface free energy. The influence of the structure and composition of the copolymers on the surface free energy and the work of adhesion to polar and dispersive test liquids has been demonstrated. At a smooth surface, the polymer coatings based on the functional copolymers have exhibited low surface free energy (down to 19 mN/m) and to ensure the high-hydrophobic wetting state with contact angles up to 105°. The stability of the superhydrophobic state of the polymer coatings at the textured aluminum surface (the AMG2M grade) with initial wetting angles up to 168° has been investigated.

Abstract Image

Abstract Image

甲基丙烯酸缩水甘油酯和甲基丙烯酸烷基酯共聚物的组成对涂层自由能和冻干特性的影响
摘要 有人建议使用甲基丙烯酸缩水甘油酯和烷基甲基丙烯酸酯的反应共聚物(烷基取代基的长度不同(С6-С18))来替代含氟改性剂,以有效降低表面自由能。共聚物的结构和组成对表面自由能以及极性和分散性测试液体粘附力的影响已得到证实。在光滑表面上,基于功能共聚物的聚合物涂层显示出较低的表面自由能(低至 19 mN/m),并确保了接触角高达 105°的高疏水性润湿状态。我们还研究了聚合物涂层在纹理铝表面(AMG2M 级)超疏水状态的稳定性,其初始润湿角可达 168°。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信