Recent advances in metal-mediated oxidations with mCPBA

IF 1.6 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Transition Metal Chemistry Pub Date : 2024-06-24 DOI:10.1007/s11243-024-00593-8

Ravi Varala, Surbhi Dhadda, Vittal Seema, Mohammed Amanullah, Mohamed Hussien, Mohammed Mujahid Alam

引用次数: 0

Abstract

Among the various peroxides that are available, meta-chloroperbenzoic acid (mCPBA) is an effective oxidizing reagent that is used in a variety of oxidative transformations, including rearrangements, oxidation of different functional groups, and the formation of carbon–carbon and carbon–heteroatom bonds. This mini-review aims to emphasize on properties, structures, and reactivities of intermediate species involved in the representative metal-assisted contributions of mCPBA in organic synthesis and catalysis along with its scope, merits, and demerits of the reaction from mid-2015 to date.

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用 mCPBA 进行金属介导氧化的最新进展

在现有的各种过氧化物中，偏氯过苯甲酸（mCPBA）是一种有效的氧化试剂，可用于各种氧化转化，包括重排、不同官能团的氧化以及碳-碳键和碳-异原子键的形成。这篇微型综述旨在强调 mCPBA 在有机合成和催化中的代表性金属辅助贡献所涉及的中间物种的性质、结构和反应活性，以及从 2015 年年中至今该反应的范围、优点和缺点。图表摘要

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Transition Metal Chemistry 化学-无机化学与核化学

CiteScore

3.60

自引率

0.00%

发文量

审稿时长

1.3 months

期刊介绍： Transition Metal Chemistry is an international journal designed to deal with all aspects of the subject embodied in the title: the preparation of transition metal-based molecular compounds of all kinds (including complexes of the Group 12 elements), their structural, physical, kinetic, catalytic and biological properties, their use in chemical synthesis as well as their application in the widest context, their role in naturally occurring systems etc. Manuscripts submitted to the journal should be of broad appeal to the readership and for this reason, papers which are confined to more specialised studies such as the measurement of solution phase equilibria or thermal decomposition studies, or papers which include extensive material on f-block elements, or papers dealing with non-molecular materials, will not normally be considered for publication. Work describing new ligands or coordination geometries must provide sufficient evidence for the confident assignment of structural formulae; this will usually take the form of one or more X-ray crystal structures.