Activated sawdust as a sustainable solution for mercury removal in contaminated waters

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Fatima Zohra Bouzid, Aouatef Driouch, Hakim Aguedal, Abdallah Aziz, Abdelkader Iddou, Abdelhadi Bentouami, Anita Thakur, Gaurav Goel, Mohamed El Amine Elaissaoui Elmeliani
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Abstract

This study investigates the synthesis of a cost-effective sawdust-derived adsorbent through an acidic and alkaline treatments, providing an alternative material for water purification specially for mercury removal. The Scanning Electron Microscopy revealed a porous structure, the Fourier transform infrared spectroscopy confirmed the existence of wide range of functional groups, and the Thermogravimetric analysis affirmed its thermal stability. Notably, the adsorbent exhibited an exceptional mercury uptake capacity of 528 mg/g according to Langmuir isotherm model, surpassing conventional low-cost alternatives. The kinetics adsorption data were modeled by nine kinetic models, likewise the adsorption isotherms data were modeled by eight isotherm models. The thermodynamic parameters, indicates that the removal process of mercury by activated sawdust is spontaneous and exothermic nature, occurs in less randomness at this interface. This research underscores the adsorbent’s promise for mercury removal, making a significant contribution to sustainable environmental remediation practices. The economic viability, coupled with its impressive performance metrics, positions this sawdust-derived adsorbent as a promising candidate for addressing water contamination challenges.

Abstract Image

活性锯屑作为受污染水体除汞的可持续解决方案
本研究探讨了通过酸性和碱性处理合成一种具有成本效益的锯屑衍生吸附剂,为水净化特别是汞去除提供了一种替代材料。扫描电子显微镜显示了该吸附剂的多孔结构,傅立叶变换红外光谱证实了其存在多种官能团,热重分析证实了其热稳定性。值得注意的是,根据 Langmuir 等温线模型,该吸附剂的汞吸收能力高达 528 毫克/克,超过了传统的低成本替代品。动力学吸附数据由 9 个动力学模型建模,吸附等温线数据同样由 8 个等温线模型建模。热力学参数表明,活性锯屑对汞的去除过程是自发的、放热的,在该界面上发生的随机性较小。这项研究强调了吸附剂在去除汞方面的前景,为可持续的环境修复实践做出了重大贡献。其经济可行性及其令人印象深刻的性能指标,使这种源于锯末的吸附剂成为应对水污染挑战的有前途的候选材料。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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