Regioselective difunctionalization of alkenes with CF2FG Moieties

IF 1.7 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Fluorine Chemistry Pub Date : 2024-07-01 DOI:10.1016/j.jfluchem.2024.110296

Thomas Castanheiro, Tatiana Besset

引用次数: 0

Abstract

The organofluorine chemistry field has steadily increased over the years. In particular, the difunctionalization of unsaturated compounds is an efficient pathway toward the formation of regioselective and highly functionalized aliphatic compounds. This review depicts the recent advances made for simultaneously forming C−FG¹ and C−CF₂FG² on alkenes (FG = functional group) by catalysis. This review highlights approaches involving transition metal-catalyzed transformations and one electron manifold.

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烯烃与 CF2FG 分子的区域选择性双官能化

多年来，有机氟化学领域的研究稳步发展。其中，不饱和化合物的二官能化是形成具有区域选择性的高官能化脂肪族化合物的有效途径。本综述介绍了通过催化在烯（FG = 官能团）上同时形成 C-FG1 和 C-CF2FG2 的最新进展。本综述重点介绍涉及过渡金属催化转化和单电子歧管的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Fluorine Chemistry 化学-无机化学与核化学

CiteScore

3.80

自引率

10.50%

发文量

审稿时长

33 days

期刊介绍： The Journal of Fluorine Chemistry contains reviews, original papers and short communications. The journal covers all aspects of pure and applied research on the chemistry as well as on the applications of fluorine, and of compounds or materials where fluorine exercises significant effects. This can include all chemistry research areas (inorganic, organic, organometallic, macromolecular and physical chemistry) but also includes papers on biological/biochemical related aspects of Fluorine chemistry as well as medicinal, agrochemical and pharmacological research. The Journal of Fluorine Chemistry also publishes environmental and industrial papers dealing with aspects of Fluorine chemistry on energy and material sciences. Preparative and physico-chemical investigations as well as theoretical, structural and mechanistic aspects are covered. The Journal, however, does not accept work of purely routine nature. For reviews and special issues on particular topics of fluorine chemistry or from selected symposia, please contact the Regional Editors for further details.