Geology, geochemistry, zircon and garnet U–Pb geochronology, and C–O–S–Pb–Hf isotopes of the Guojiagou Pb–Zn deposit, West Qinling Belt, Central China: New constraints on district-wide mineralization

IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS
Zhao-yang Song , Yan-chen Yang , Shi-jiong Han , Yan Zheng , Zi-jian Zeng , Tian-wen Chen , Guo-bin Zhang
{"title":"Geology, geochemistry, zircon and garnet U–Pb geochronology, and C–O–S–Pb–Hf isotopes of the Guojiagou Pb–Zn deposit, West Qinling Belt, Central China: New constraints on district-wide mineralization","authors":"Zhao-yang Song ,&nbsp;Yan-chen Yang ,&nbsp;Shi-jiong Han ,&nbsp;Yan Zheng ,&nbsp;Zi-jian Zeng ,&nbsp;Tian-wen Chen ,&nbsp;Guo-bin Zhang","doi":"10.1016/j.gexplo.2024.107534","DOIUrl":null,"url":null,"abstract":"<div><p>The Guojiagou Pb–Zn deposit is located in Li County, Gansu Province, northwestern China. The ores consist of skarn and vein types, with the skarn type occurring at the contact zone between granodiorite and marble, and the vein type hosted in the extension faults within the Triassic Huashiguan Formation limestone. Granodiorite samples from the Weijiazhuang pluton show high ratios of Sr/Y (32.25–43.44) and (La/Yb)<sub>N</sub> (15.7–16.5), small Eu anomalies (δEu = 0.73–0.80), high concentrations of Mg<sup>#</sup> (57.6–64.2), Cr (100–110 ppm), and Ni (15.9–16.6 ppm), abundant mafic micro-granular enclaves, and have zircon εHf<sub>(t)</sub> values of −1.9 to −4.6 and T<sub>DM2</sub> of 1149.6 to 1285 Ma. This suggests that the Weijiazhuang granodiorites were generated by the partial melting of the Meso-Proterozoic high-K basaltic lower crust with the addition of mantle-sourced melts. The ore-forming process can be subdivided into five stages: prograde skarn (stage I), retrograde skarn (stage II), quartz-sulfide (stage III), sphalerite-calcite (stage IV), and quartz-calcite (stage V). The δ<sup>13</sup>C values range from −5.1 to −1.3 ‰ and δ<sup>18</sup>O values range from −4 to 18.6 ‰ in calcites, suggesting a mixed source of magma, limestone, and pore or basinal water for CO<sub>3</sub><sup>2−</sup>. The δ<sup>34</sup>S values (6–7.7 ‰) of sulfides indicate that sulfur mainly originated from magma, with a minor contribution from host limestone. The Pb isotopes of sulfides from stages III and IV (<sup>208</sup>Pb/<sup>204</sup>Pb = 38.176–39.218, <sup>207</sup>Pb/<sup>204</sup>Pb = 15.889–15.678, and <sup>206</sup>Pb/<sup>204</sup>Pb = 18.147–18.903) showed mixed sources of crust and mantle. The Weijiazhuang pluton and Guojiagou Pb–Zn deposit yield ages of 220 ± 1.8 Ma (MSWD = 0.35) and 213 ± 3.0 Ma (MSWD = 1.5), respectively, obtained by zircon and garnet LA–ICP–MS U–Pb analysis. These results indicate that the Guojiagou Pb–Zn deposit formed in a <em>syn</em>-collisional tectonic regime during the Late Triassic. Based on the data presented in this study and previous research on mineralization in the eastern West Qinling Orogen, we conclude that the Guojiagou Pb–Zn deposit is a typical skarn-type deposit and that Pb–Zn mineralization in the eastern West Qinling Orogen is closely related to Triassic magmatism, which provided not only thermal energy but also ore-forming materials and fluids.</p></div>","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":null,"pages":null},"PeriodicalIF":3.4000,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Geochemical Exploration","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S037567422400150X","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
引用次数: 0

Abstract

The Guojiagou Pb–Zn deposit is located in Li County, Gansu Province, northwestern China. The ores consist of skarn and vein types, with the skarn type occurring at the contact zone between granodiorite and marble, and the vein type hosted in the extension faults within the Triassic Huashiguan Formation limestone. Granodiorite samples from the Weijiazhuang pluton show high ratios of Sr/Y (32.25–43.44) and (La/Yb)N (15.7–16.5), small Eu anomalies (δEu = 0.73–0.80), high concentrations of Mg# (57.6–64.2), Cr (100–110 ppm), and Ni (15.9–16.6 ppm), abundant mafic micro-granular enclaves, and have zircon εHf(t) values of −1.9 to −4.6 and TDM2 of 1149.6 to 1285 Ma. This suggests that the Weijiazhuang granodiorites were generated by the partial melting of the Meso-Proterozoic high-K basaltic lower crust with the addition of mantle-sourced melts. The ore-forming process can be subdivided into five stages: prograde skarn (stage I), retrograde skarn (stage II), quartz-sulfide (stage III), sphalerite-calcite (stage IV), and quartz-calcite (stage V). The δ13C values range from −5.1 to −1.3 ‰ and δ18O values range from −4 to 18.6 ‰ in calcites, suggesting a mixed source of magma, limestone, and pore or basinal water for CO32−. The δ34S values (6–7.7 ‰) of sulfides indicate that sulfur mainly originated from magma, with a minor contribution from host limestone. The Pb isotopes of sulfides from stages III and IV (208Pb/204Pb = 38.176–39.218, 207Pb/204Pb = 15.889–15.678, and 206Pb/204Pb = 18.147–18.903) showed mixed sources of crust and mantle. The Weijiazhuang pluton and Guojiagou Pb–Zn deposit yield ages of 220 ± 1.8 Ma (MSWD = 0.35) and 213 ± 3.0 Ma (MSWD = 1.5), respectively, obtained by zircon and garnet LA–ICP–MS U–Pb analysis. These results indicate that the Guojiagou Pb–Zn deposit formed in a syn-collisional tectonic regime during the Late Triassic. Based on the data presented in this study and previous research on mineralization in the eastern West Qinling Orogen, we conclude that the Guojiagou Pb–Zn deposit is a typical skarn-type deposit and that Pb–Zn mineralization in the eastern West Qinling Orogen is closely related to Triassic magmatism, which provided not only thermal energy but also ore-forming materials and fluids.

中国中部西秦岭带郭家沟铅锌矿床的地质、地球化学、锆石和石榴石U-Pb地质年代和C-O-S-Pb-Hf同位素:全区成矿新约束
郭家沟铅锌矿位于中国西北部甘肃省礼县。矿石由矽卡岩型和脉石型组成,矽卡岩型出现在花岗闪长岩与大理岩的接触带,脉石型赋存于三叠系花石关地层石灰岩的延伸断层中。魏家庄岩体的花岗闪长岩样品显示出较高的 Sr/Y 比值(32.25-43.44)和 (La/Yb)N 比值(15.7-16.5),较小的 Eu 异常(δEu = 0.73-0.80),较高的 Mg# 浓度(57.6-64.2)、Cr 浓度(57.6-64.2)和 Eu 浓度(δEu = 0.73-0.80)。6-64.2)、铬(100-110 ppm)和镍(15.9-16.6 ppm),丰富的岩浆岩微小粒状飞地,锆石εHf(t)值为-1.9至-4.6,TDM2为1149.6至1285 Ma。这表明魏家庄花岗闪长岩是由中新生代高K玄武岩下地壳部分熔融并加入地幔源熔体而形成的。成矿过程可细分为五个阶段:原生矽卡岩(第一阶段)、逆行矽卡岩(第二阶段)、石英-硫化物(第三阶段)、闪锌矿-方解石(第四阶段)和石英-方解石(第五阶段)。方解石中的δ13C 值范围为 -5.1 至 -1.3 ‰,δ18O 值范围为 -4 至 18.6 ‰,表明 CO32- 的来源是岩浆、石灰岩、孔隙水或基底水的混合。硫化物的δ34S值(6-7.7‰)表明硫主要来自岩浆,少量来自寄主石灰岩。三期和四期硫化物的铅同位素(208Pb/204Pb = 38.176-39.218,207Pb/204Pb = 15.889-15.678,206Pb/204Pb = 18.147-18.903)表明硫化物来源于地壳和地幔。通过锆石和石榴石LA-ICP-MS U-Pb分析,魏家庄岩体和郭家沟铅锌矿床的年龄分别为220±1.8Ma(MSWD=0.35)和213±3.0Ma(MSWD=1.5)。这些结果表明,郭家沟铅锌矿床形成于晚三叠世的同步碰撞构造体系中。根据本研究提供的数据和以往对西秦岭造山带东部成矿作用的研究,我们认为郭家沟铅锌矿是典型的矽卡岩型矿床,西秦岭造山带东部铅锌矿的成矿作用与三叠纪岩浆活动密切相关,三叠纪岩浆活动不仅提供了热能,还提供了成矿物质和流体。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of Geochemical Exploration
Journal of Geochemical Exploration 地学-地球化学与地球物理
CiteScore
7.40
自引率
7.70%
发文量
148
审稿时长
8.1 months
期刊介绍: Journal of Geochemical Exploration is mostly dedicated to publication of original studies in exploration and environmental geochemistry and related topics. Contributions considered of prevalent interest for the journal include researches based on the application of innovative methods to: define the genesis and the evolution of mineral deposits including transfer of elements in large-scale mineralized areas. analyze complex systems at the boundaries between bio-geochemistry, metal transport and mineral accumulation. evaluate effects of historical mining activities on the surface environment. trace pollutant sources and define their fate and transport models in the near-surface and surface environments involving solid, fluid and aerial matrices. assess and quantify natural and technogenic radioactivity in the environment. determine geochemical anomalies and set baseline reference values using compositional data analysis, multivariate statistics and geo-spatial analysis. assess the impacts of anthropogenic contamination on ecosystems and human health at local and regional scale to prioritize and classify risks through deterministic and stochastic approaches. Papers dedicated to the presentation of newly developed methods in analytical geochemistry to be applied in the field or in laboratory are also within the topics of interest for the journal.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信