Nickel, chromium, and cobalt in soils developed on nickel laterites near an abandoned mining area in southern Czech Republic

IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS
Vojtěch Ettler , Zuzana Pipková , Jindřich Kvapil , Martin Mihaljevič , Petr Drahota , Aleš Vaněk , Vít Penížek
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Abstract

Geochemical anomalies are gaining importance due to the Europe's renewed prospecting activities for technologically critical metals, such as nickel (Ni) and cobalt (Co). In this context, soils developed on Ni laterites near old open pit mining and exploration works near Křemže in southern Czech Republic were investigated using multi-method approach to assess the distribution, solid speciation, and (bio)availability of the trace metals, with a particular focus on Ni, chromium (Cr), and Co. The total concentrations of metals in the studied soils (Ni: 170–4950 mg/kg, Cr: 56–1190 mg/kg, Co: 14–424 mg/kg) exceeded the median world regulatory guideline values (Ni: 112 mg/kg; Cr: 250 mg/kg; Co: 50 mg/kg) as well as the Czech concentration limits for agricultural soils for most of the samples. The concentration of metals in the soil profiles generally increased as a function of depth with surface horizons in agricultural plots homogenized by ploughing. The effect of a former open pit mine (already closed for ca 80 years) on the vertical distribution of metallic elements has not been demonstrated. The extractable metals were relatively low (extraction efficiency order: water < DTPA < EDTA). The mean EDTA-extractable values corresponded to 4.2 % Nitot, 8.6 % Cotot, and only 0.14 % Crtot. This contrasting metal availability is strictly related to the metal speciation in the solid phase. The primary minerals (olivine, clinopyroxene) are highly weathered to secondary phyllosilicates (lizardite, talc) and Fe oxyhydroxides and Mn oxides, all representing important carriers for Ni. Cobalt was exclusively hosted by Mn oxides, and the less mobile Cr was mainly bound in insoluble phases, likely spinel-family oxides. Despite the relatively low metal availability, elevated concentrations of Ni in the crop biomass (86 mg/kg) collected in the agricultural area suggest a metal uptake from the soil, which should be further investigated in detail.

Abstract Image

捷克共和国南部废弃矿区附近红土镍矿土壤中的镍、铬和钴
由于欧洲对镍(Ni)和钴(Co)等关键技术金属重新开展勘探活动,地球化学异常现象变得越来越重要。在此背景下,采用多种方法对捷克共和国南部克热姆泽附近旧露天采矿和勘探工程附近的红土镍矿土壤进行了调查,以评估痕量金属的分布、固体标本和(生物)可用性,重点是镍、铬(Cr)和钴。所研究土壤中的金属总浓度(镍:170-4950 毫克/千克;铬:56-1190 毫克/千克;钴:14-424 毫克/千克)超过了世界法规指导值的中位数(镍:112 毫克/千克;铬:250 毫克/千克;钴:50 毫克/千克),大多数样本中的金属浓度也超过了捷克农业土壤的浓度限值。土壤剖面中的金属浓度一般随着深度的增加而增加,农业用地的地表地层因犁耕而变得均匀。前露天矿(已关闭约 80 年)对金属元素垂直分布的影响尚未得到证实。可萃取的金属相对较少(萃取效率顺序为:水 < DTPA < EDTA)。乙二胺四乙酸(EDTA)萃取的平均值分别为 4.2 % Nitot、8.6 % Cot 和仅 0.14 % Crtot。这种截然不同的金属可得性与固相中的金属种类密切相关。原生矿物质(橄榄石、倩辉石)被高度风化成次生硅铝酸盐(蜥蜴石、滑石)、铁氧氢氧化物和锰氧化物,它们都是镍的重要载体。钴完全被锰氧化物所容纳,而流动性较差的铬主要结合在不溶性相中,很可能是尖晶石族氧化物。尽管金属的可用性相对较低,但在农业区采集的作物生物质中,镍的浓度较高(86 毫克/千克),这表明土壤中存在金属吸收,应对此进行进一步的详细研究。
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来源期刊
Journal of Geochemical Exploration
Journal of Geochemical Exploration 地学-地球化学与地球物理
CiteScore
7.40
自引率
7.70%
发文量
148
审稿时长
8.1 months
期刊介绍: Journal of Geochemical Exploration is mostly dedicated to publication of original studies in exploration and environmental geochemistry and related topics. Contributions considered of prevalent interest for the journal include researches based on the application of innovative methods to: define the genesis and the evolution of mineral deposits including transfer of elements in large-scale mineralized areas. analyze complex systems at the boundaries between bio-geochemistry, metal transport and mineral accumulation. evaluate effects of historical mining activities on the surface environment. trace pollutant sources and define their fate and transport models in the near-surface and surface environments involving solid, fluid and aerial matrices. assess and quantify natural and technogenic radioactivity in the environment. determine geochemical anomalies and set baseline reference values using compositional data analysis, multivariate statistics and geo-spatial analysis. assess the impacts of anthropogenic contamination on ecosystems and human health at local and regional scale to prioritize and classify risks through deterministic and stochastic approaches. Papers dedicated to the presentation of newly developed methods in analytical geochemistry to be applied in the field or in laboratory are also within the topics of interest for the journal.
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