Exploring kinetics and mass transfer in photocatalytic CO2 reduction: Impact of photocatalyst loading and stirrer speed

Abstract

CO₂ photocatalytic reduction is a potential and promising technology to reduce the level of the greenhouse gas in the atmosphere but also as an alternative and renewable fuel resource. However, the products yield of the reaction is still low and the identification of the optimal operating conditions that affect the process are still needed to be determined. This study investigates the impact of key operational parameters, specifically photocatalyst concentration and stirring speed, on the photocatalytic reduction of CO₂ in a slurry batch photoreactor utilizing synthesized TiO₂. A simplified photocatalytic kinetic model, incorporating the radiation field within the photoreactor, was developed, considering mass transfer from liquid to gas phase for the primary detected reaction products (CO, CH₄, and H₂). The proposed models elucidate the influence of different operating conditions on product yields. Stirring speed, controlled by a magnetic stirrer, impacts the gas–liquid mass transfer rate. Increased liquid phase stirring speed ensures faster species transport to the gas phase, with a diminishing effect beyond 900 rpm. TiO₂ photocatalyst mass concentration influences the available total active surface and irradiation absorbance in the photoreactor volume. Optimal product yields were observed at the lowest tested photocatalyst concentration (0.5 g · L^-1), indicating improved irradiation distribution and reduced particle agglomeration, resulting in higher available active surface for the reaction. The calculation model successfully predicted product yields even with lower photocatalyst concentration of 0.25 g · L^-1, with marginal increases in predicted yields. These findings provide valuable insights for scaling up and optimizing the CO₂ photocatalytic reduction process, offering a foundation for future research.