Auto-Optimized Electro-Flow Reactor Platform for the in-situ Reduction of P(V) Oxide to P(III) and Their Application.

IF 3.5 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - An Asian Journal Pub Date : 2024-06-24 DOI:10.1002/asia.202400438

Mandeep Purwa, Gaykwad Chandrakanth, Abhilash Rana, Amirreza Mottafegh, Sanjeev Kumar, Dong-Pyo Kim, Ajay K Singh

引用次数: 0

Abstract

Trivalent phosphine catalysis is mostly utilized to activate the carbon-carbon multiple bonds to form carbanion intermediate species and is highly sensitive to certain variables. Random manual multi-variables are critical for understanding the batch disabled regeneration of trivalent phosphine chemistry. We need the artificial intelligence-based system which can change the variable based on previously conducted failed experiment. Herein, we report an auto-optimized electro-micro-flow reactor platform for the in-situ reduction of stable P(V) oxide to sensitive P(III) and further utilized the method for Corey-Fuchs reaction.

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原位将氧化铅（V）还原成氧化铅（III）的自动优化电流式反应器平台及其应用。

三价膦催化主要用于活化碳-碳多键，形成碳阴离子中间体，对某些变量高度敏感。随机手动多变量对于理解三价膦化学的批量禁用再生至关重要。我们需要基于人工智能的系统，它可以根据之前进行的失败实验改变变量。在此，我们报告了一种自动优化的电动微流反应器平台，用于将稳定的 P(V) 氧化物原位还原为敏感的 P(III)，并进一步用于科里-富克斯反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemistry - An Asian Journal 化学-化学综合

CiteScore

7.00

自引率

2.40%

发文量

535

审稿时长

1.3 months

期刊介绍： Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).

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