Iron Oxyhydroxide-Rich Hydrothermal Deposits at the High-Temperature Fåvne Vent Field, Mohns Ridge

IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS
Caroline Gini, John W. Jamieson, Eoghan P. Reeves, Amy Gartman, Thibaut Barreyre, Michael G. Babechuk, Steffen L. Jørgensen, Katleen Robert
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Abstract

The recently discovered Fåvne vent field, located at 3,040 m depth on the slow-spreading Mohns mid-ocean ridge between Greenland and Norway, is a high-temperature (≥250°C) vent field that is characterized by Fe oxyhydroxide-rich and S-poor chimneys and mounds. The vent field is located on both the hanging wall and footwall of a normal fault with a ∼1.5 km throw that forms the western edge of the ∼20 km wide ridge axial valley. Data collected during exploration of the site using a remotely operated vehicle as well as mineralogical and geochemical analyses of rock samples and sediments are used to characterize the geological setting of the vent field and composition of the hydrothermal deposits. The chimney walls are highly porous and lack defined chalcopyrite lined conduits, typical of high-temperature chimneys. Overall, abundant Fe oxyhydroxide precipitation at high-temperature vents at Fåvne reflects an excess of Fe over reduced S in the fluid, leading to precipitation of Fe oxide and oxyhydroxide minerals at high to moderate temperature vents (>100°C), and as microbially mediated and abiotic precipitation of Fe oxyhydroxide minerals at low-temperature diffuse vents (<100°C). The mounds and chimneys exhibit low base metal and reduced S concentrations relative to globally averaged seafloor deposits and suggest subseafloor mixing of hydrothermal fluid with seawater, causing metal sulfide precipitation. Cobalt enrichment at Fåvne may reflect a subsurface influence of an ultramafic substrate on circulating fluids, although ultramafic rocks are absent on the seafloor and no other elements typical of ultramafic deposits are present.

Abstract Image

莫恩斯海脊高温法文喷口区富含氧化氢铁的热液矿床
最近发现的 Fåvne 喷口区位于格陵兰和挪威之间缓慢扩张的莫恩斯洋中脊上 3,040 米深处,是一个高温(≥250°C)喷口区,其特征是富含氢氧化铁和贫S的烟囱和土丘。喷口区位于一个正断层的悬壁和底壁,正断层的走向≥1.5千米,构成了≥20千米宽的山脊轴谷的西部边缘。利用遥控潜水器对该地点进行勘探时收集的数据,以及对岩石样本和沉积物进行的矿物学和地球化学分析,用于描述喷口区的地质环境和热液沉积物的成分。烟囱壁孔隙很大,缺乏明确的黄铜矿内衬导管,这是高温烟囱的典型特征。总的来说,法文高温喷口大量的氢氧化铁沉淀反映了流体中铁的含量超过了还原性S,导致氧化铁和氢氧化铁矿物在高温至中温喷口(100°C)沉淀,以及在低温扩散喷口(100°C)微生物介导和非生物沉淀的氢氧化铁矿物。与全球平均海底沉积物相比,土丘和烟囱显示出较低的贱金属浓度和较低的 S 浓度,表明热液与海水在海底下混合,导致金属硫化物沉淀。尽管海底没有超基性岩,也没有超基性岩沉积物所特有的其他元素,但法文的钴富集可能反映了超基性岩基质对循环流体的影响。
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来源期刊
Geochemistry Geophysics Geosystems
Geochemistry Geophysics Geosystems 地学-地球化学与地球物理
CiteScore
5.90
自引率
11.40%
发文量
252
审稿时长
1 months
期刊介绍: Geochemistry, Geophysics, Geosystems (G3) publishes research papers on Earth and planetary processes with a focus on understanding the Earth as a system. Observational, experimental, and theoretical investigations of the solid Earth, hydrosphere, atmosphere, biosphere, and solar system at all spatial and temporal scales are welcome. Articles should be of broad interest, and interdisciplinary approaches are encouraged. Areas of interest for this peer-reviewed journal include, but are not limited to: The physics and chemistry of the Earth, including its structure, composition, physical properties, dynamics, and evolution Principles and applications of geochemical proxies to studies of Earth history The physical properties, composition, and temporal evolution of the Earth''s major reservoirs and the coupling between them The dynamics of geochemical and biogeochemical cycles at all spatial and temporal scales Physical and cosmochemical constraints on the composition, origin, and evolution of the Earth and other terrestrial planets The chemistry and physics of solar system materials that are relevant to the formation, evolution, and current state of the Earth and the planets Advances in modeling, observation, and experimentation that are of widespread interest in the geosciences.
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