A Study of Phosphorus–Nitrogen-Containing Modifier with Polyfunctional Action in Polymer Systems

IF 0.58 Q4 Materials Science
N. A. Keibal, V. F. Kablov, V. G. Kochetkov, O. M. Novopol’tseva, K. S. Kazaryan, V. I. Stryukova
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引用次数: 0

Abstract

The paper is devoted to the development of a new phosphorus–nitrogen-containing fire retardant with multifunctional action, which is a product of the interaction of dimethylphosphite and dicyandiamide (DDP). The resulting product has a close-to-optimal ratio of nitrogen and phosphorus atoms, which determines its adhesive, thermal stabilizing, and antipyretic activity. DDP has a positive effect on the fire- and heat-protective properties of the material: the time for heating the unheated surface of the sample to 100°C increases by 39–57%, and the linear burning rate decreases by 17–21%. It has been shown that the strength of the adhesive joint increases by an average of 30–70% and the composition containing DDP exhibits consistently better adhesive strength than the original adhesive composition up to 80°C.

Abstract Image

Abstract Image

聚合物体系中具有多功能作用的含磷氮改性剂研究
本文致力于开发一种具有多功能作用的新型含磷氮阻燃剂,它是亚磷酸二甲酯和双氰胺(DDP)相互作用的产物。由此产生的产品具有接近最佳比例的氮原子和磷原子,这决定了它具有粘合性、热稳定性和解热活性。DDP 对材料的防火和防热性能有积极影响:样品未加热表面加热到 100°C 的时间增加了 39-57%,线性燃烧率降低了 17-21%。研究表明,粘合接头的强度平均提高了 30-70%,含有 DDP 的组合物在高达 80°C 的温度下显示出的粘合强度始终优于原始粘合组合物。
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来源期刊
Polymer Science, Series D
Polymer Science, Series D Materials Science-Polymers and Plastics
CiteScore
0.80
自引率
0.00%
发文量
87
期刊介绍: Polymer Science, Series D  publishes useful description of engineering developments that are related to the preparation and application of glues, compounds, sealing materials, and binding agents, articles on the adhesion theory, prediction of the strength of adhesive joints, methods for the control of their properties, synthesis, and methods of structural modeling of glued joints and constructions, original articles with new scientific results, analytical reviews of the modern state in the field.
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