Synthesis and thermophysical property characterization of aqueous graphene quantum dot dispersions for air-conditioning applications

Abstract

Air-conditioning systems are on track to demand most of the electricity consumed by buildings around the world. The authors propose that dispersing quantum dots into the chilled water loops of air-conditioners represents a path towards improving the efficiency of air-conditioners. As such, the thermophysical properties of carbon-based quantum dot ‘nanofluids’ (e.g., nanoparticles dispersed in liquids) are presented in this study for sub-ambient temperatures (5–15°C)—an under-explored temperature range which requires understanding for air-conditioning applications. This study also explores dispersion stability and materials compatibility—another under-explored area in the literature which is required for commercial uptake. In this study, carbon quantum dots were synthesized via the hydrothermal route and characterized with UV–Vis, FT-IR, Raman spectroscopy, and TEM. Next, the thermophysical properties of specific heat capacity, thermal conductivity, and viscosity of the nanofluids were experimentally measured between 5 and 15°C (not previously reported for aqueous quantum dots). The highest thermal conductivity enhancement was ∼11% (compared to DI water) for 0.3 wt.% at ∼11 °C. Finally, the stability of the fluid was monitored over time and after exposing the fluids to common materials used in air-conditioning systems (e.g., copper, brass, and stainless steel). Unchanged UV–Vis spectra and the lack of sedimentation indicate that the developed dispersions are indeed suitable for chilled water air-conditioning applications.