Experimental study of the effect of the temperature of inert gases on the intensity of thermal decomposition of rubber

G. I. Pavlov, Y. Vankov, D. A. Telyashov, D. A. Zaynutdinova, A. Mukatdarov
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Abstract

THE PURPOSE. An experimental method is used to evaluate the effect of the temperature of inert gases on the rate of thermal decomposition of waste rubber products (fragments of a car tire) upon their direct contact.METHODS. The research was carried out on a test firing stand at a stationary mode of gas movement in the temperature range from 300 °C to 500 °C. The initial weight of the rubber was 4 grams. The thermal decomposition of rubber was carried out due to the thermal energy of inert gas released during the combustion of a propanebutane mixture with air at α = 1.1...1.15. The consumption of fuel and oxidizer remained constant, the change in gas temperature was carried out by heat exchange of hot gases and water in the heat exchanger.RESULTS. Metodology of conducting experiments, the object of research under the study, results of the research and their analysis are described in the article. The main parameters were selected: the rate of decrease in rubber mass depending on the temperature of the gases, the limiting value of the gas temperature at which sulfur in solid form remains in the decomposed part of the rubber.CONCLUSION. It was found that with increasing temperature of the inert gas, the rate of thermal decomposition of rubber increases. When rubber is in a gaseous environment in the temperature range from 450 0C to 500 0C, the sulfur content in the solid residue remains practically unchanged. The average rate of pyrolysis was 0.02 kg/h, which is 6 times higher than the rate of pyrolysis in the retort (0.003 kg/h).
惰性气体温度对橡胶热分解强度影响的实验研究
目的: 采用实验方法评估惰性气体温度对废橡胶产品(汽车轮胎碎片)直接接触时热分解速率的影响。采用实验方法评估惰性气体温度对废橡胶产品(汽车轮胎碎片)直接接触时热分解速率的影响。 研究在试验烧制台上进行,气体运动模式为静止模式,温度范围为 300 °C 至 500 °C。橡胶的初始重量为 4 克。在 α = 1.1...1.15 时,丙烷丁烷混合物与空气燃烧时释放的惰性气体热能导致橡胶热分解。燃料和氧化剂的消耗量保持不变,气体温度的变化是通过热交换器中热气和水的热交换实现的。文章介绍了实验方法、研究对象、研究结果及其分析。选定的主要参数包括:橡胶质量随气体温度降低的速率、橡胶分解部分仍含有固态硫磺的气体温度极限值。研究发现,随着惰性气体温度的升高,橡胶的热分解速率会增加。当橡胶处于温度范围为 450 0C 至 500 0C 的气体环境中时,固体残留物中的硫含量几乎保持不变。热分解的平均速率为 0.02 kg/h,比在蒸馏罐中的热分解速率(0.003 kg/h)高出 6 倍。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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