Development of a Novel Pressure Vessel System for the Simulation of Starch Expansion – Methylated and Regular Waxy Corn Starch Behave Significantly Different With and Without Cellulose Inclusion

J. Richter, S. Saunders, Marin Ikuse, Sean M. Finnie, Girish M. Ganjyal
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Abstract

Fortification of direct‐expanded products with insoluble fiber generally leads to decreased expansion. Understanding the interactions between starches and fibers can help to include more fiber into puffed products. A pressure vessel setup is developed to allow for a small‐scale expansion process. Because trends for the expansion ability during the simulated process are similar to those during extrusion, the setup has been proven to be suitable for understanding the occurrences during extrusion. Elimination of hydroxyl groups through starch methylation can help to understand the role of hydrogen bonding during expansion. Nonmethylated and methylated starch are tested for their expansion at cellulose levels of 0%, 5%, and 20% on a weight basis. The specific volume of the obtained samples is used to determine the degree of expansion. The nonmethylated starch sample exhibits a specific volume of 16.3 ± 1.8 cm3 g−1, which is almost three times higher than the one of the methylated sample (≈6.0 cm3 g−1). Possible reasons for this decrease are the elimination of hydroxyl groups capable of forming hydrogen bonds or the significantly higher viscosity of the methylated starch. While fortification with 5% cellulose does not affect the expansion, 20% cellulose greatly reduces the specific volume for both starches.
开发用于模拟淀粉膨胀的新型压力容器系统 - 含有和不含纤维素的甲基化和普通蜡质玉米淀粉表现明显不同
在直接膨化产品中添加不溶性纤维通常会导致膨化度降低。了解淀粉和纤维之间的相互作用有助于在膨化产品中添加更多纤维。为实现小规模膨化过程,开发了一种压力容器装置。由于模拟过程中的膨胀能力趋势与挤压过程中的趋势相似,因此该装置已被证明适用于了解挤压过程中发生的情况。通过淀粉甲基化消除羟基有助于了解氢键在膨胀过程中的作用。在纤维素含量为 0%、5% 和 20% 时,对未甲基化和甲基化淀粉进行膨胀测试。所得样品的比容用于确定膨胀程度。非甲基化淀粉样品的比容为 16.3 ± 1.8 cm3 g-1,几乎是甲基化样品(≈6.0 cm3 g-1)的三倍。造成这一下降的可能原因是消除了能形成氢键的羟基,或甲基化淀粉的粘度明显更高。虽然添加 5% 的纤维素不会影响膨胀,但添加 20% 的纤维素会大大降低两种淀粉的比容。
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