METHODOLOGY FOR EXPERIMENTAL STUDY OF FIRE EXTINGUISHING OF WATER-SOLUBLE POLAR FLAMMABLE LIQUIDS

Николай Петрович Копылов, Дмитрий Вячеславович Федоткин, Е.Ю. Сушкина, А.В. Карпов, Виктория Ивановна Новикова, А.С. Тарбеев
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Abstract

На тушение пожаров водорастворимых полярных жидкостей значительное влияние оказывают их физико-химические свойства, тип пенообразователя, способы подачи его раствора. Проведен анализ современной нормативно-технической литературы, в которой рассматриваются разные экспериментальные методы определения критической и нормативной интенсивности подачи растворов пенообразователей на тушение различных видов полярных жидкостей. Даны оценки параметров наиболее репрезентативных модельных очагов пожара, коэффициентов масштабирования и безопасности. Предложены направления исследований по определению влияния физических свойств полярных жидкостей на эффективность их тушения. Modern industry produces and consumes a huge amount of various water-soluble polar liquids. According to their physical and chemical properties they can be divided into the following types: alcohols, ketones, esters, carboxylic acids, amines, aldehydes, simple esters. For these types in modern normative and technical literature there are defined experimental methods for determination of extinguishing parameters such as intensity and time of supply of solutions of alcohol-resistant blowing agents. Currently, these methods assume the use of small-scale sources of combustion from 0.25 to 7 m2. In order to extend the experimental data to real sources of fire, it is proposed to use scaling and safety factors from the range of 1.21´2.3. The choice of numerical values of the coefficients for different types of water-soluble polar liquids can be justified using the method of calculating the heat flux density from the flame torch to the mirror of the burning liquid. This method was tested in determining the optimal size of the experimental tank during gasoline combustion. Researches on estimation of influence of physical properties of water-soluble polar liquids such as density, heat of combustion, pressure of saturated vapors, boiling point and flash point on efficiency of their extinguishing by modern alcohol-resistant foaming agents are promising.
水溶性极性易燃液体灭火实验研究方法
水溶性极性液体的灭火受其物理和化学性质、发泡剂类型、发泡剂溶液供应方法的重大影响。对现代规范性技术文献进行了分析,其中考虑了确定用于扑灭不同类型极性液体的发泡剂溶液的临界和规范供应强度的不同实验方法。对最有代表性的火灾中心模型参数、比例和安全系数进行了估算。还提出了极性液体物理性质对灭火效率影响的研究方向。现代工业生产和消耗大量各种水溶性极性液体。根据其物理和化学性质,可将其分为以下类型:醇、酮、酯、羧酸、胺、醛、单酯。对于这些类型,在现代规范和技术文献中都有明确的实验方法来确定熄灭参数,如强度和提供耐醇发泡剂溶液的时间。目前,这些方法假定使用 0.25 至 7 平方米的小型燃烧源。为了将实验数据扩展到真实的火源,建议使用 1.21´2.3 范围内的比例和安全系数。可以使用计算从火焰炬到燃烧液体镜面的热流密度的方法,来合理选择不同类型水溶性极性液体的系数数值。在确定汽油燃烧过程中实验槽的最佳尺寸时,对这种方法进行了测试。对水溶性极性液体的物理性质,如密度、燃烧热、饱和蒸汽压、沸点和闪点对现代抗酒精发泡剂灭火效率的影响进行评估的研究前景广阔。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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