Haibo Li, Chen Su, Qianqian Wang, Jing Yang, Jialin Zhu, Hua Tong, Ning Zhao, Wei Liu, Gangfeng Ouyang
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引用次数: 0
Abstract
In this paper, a neutral copper iodide hybrid with unique Cu3I3 trimeric inorganic functional unit is successfully fabricated using 5,6,7,8-tetrahydroquinoxaline (L) with large steric-hindrance group as the organic ligand. The hybrid owns a one-dimensional (1D) extended polymeric structure in the form of Cu3I3(L)2. As a CuI-based hybrid, 1D-Cu3I3(L)2 has an infrequent far-red/near-infrared emission, exhibiting the potential application prospects in the field of display and night vision. Moreover, the luminescence mechanism is carefully studied by decay lifetime measurement and calculation of density of states, which is verified to be the combination of metal-to-ligand charge transfer and halide-to-ligand charge transfer.
期刊介绍:
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.