Zwitterion Intercalated Manganese Dioxide Nanosheets as High-Performance Cathode Materials for Aqueous Zinc Ion Batteries

Abstract

In this study, a novel approach is introduced to address the challenges associated with structural instability and sluggish reaction kinetics of δ-MnO₂ in aqueous zinc ion batteries. By leveraging zwitterionic betaine (Bet) for intercalation, a departure from traditional cation intercalation methods, Bet-intercalated MnO₂ (MnO₂-Bet) is synthesized. The positively charged quaternary ammonium groups in Bet form strong electrostatic interactions with the negatively charged oxygen atoms in the δ-MnO₂ layers, enhancing structural stability and preventing layer collapse. Concurrently, the negatively charged carboxylate groups in Bet facilitate the rapid diffusion of H⁺/Zn²⁺ ions through their interactions, thus improving reaction kinetics. The resulting MnO₂-Bet cathode demonstrates high specific capacity, excellent rate capability, fast reaction kinetics, and extended cycle life. This dual-function intercalation strategy significantly optimizes the electrochemical performance of δ-MnO₂, establishing it as a promising cathode material for advanced aqueous zinc ion batteries.