Deep eutectic solvents as green solvents for materials preparation

IF 9.3 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Green Chemistry Pub Date : 2024-07-01 DOI:10.1039/d4gc00136b
Dongkun Yu , Depeng Jiang , Zhimin Xue , Tiancheng Mu
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引用次数: 0

Abstract

The concept of sustainability has progressively evolved into a consensus for achieving long-term development, and the significance of solvents in regard to green chemistry and sustainable processes cannot be underestimated. Hydrogen-bonding interactions and heterogeneity at the nanoscale determine the outstanding solvating properties of deep eutectic solvents (DESs). A relatively wide electrochemical window is the prerequisite for the preparation of more materials (especially active metals) by electrodeposition in these eutectic systems. The role of DESs in the fabrication process may be chemical or physical, although the line between the two is blurred. At times, DESs function as a reducing agent, while in other cases they solely provide a liquid environment to facilitate the reaction. This review provides a set of methodologies to guide the preparation of materials with specific morphology and functions.

Abstract Image

Abstract Image

深共晶溶剂作为材料制备的绿色溶剂
可持续发展的概念已逐渐成为实现长期发展的共识,而溶剂在绿色化学和可持续工艺方面的意义不容低估。纳米尺度上的氢键相互作用和异质性决定了深共晶溶剂(DES)出色的溶解特性。相对较宽的电化学窗口是在这些共晶体系中通过电沉积制备更多材料(尤其是活性金属)的先决条件。DES 在制备过程中的作用可能是化学性的,也可能是物理性的,但两者之间的界限并不明显。有时,DES 起还原剂的作用,而在其他情况下,DES 只提供液态环境以促进反应。本综述提供了一套方法,用于指导制备具有特定形态和功能的材料。
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来源期刊
Green Chemistry
Green Chemistry 化学-化学综合
CiteScore
16.10
自引率
7.10%
发文量
677
审稿时长
1.4 months
期刊介绍: Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.
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