Electron interactions with beryllium and its hydrides

IF 1.6 3区 化学 Q3 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
Ashok Chaudhari , Harshad Bhutadia , Smruti Parikh , Minaxi Vinodkumar , Chetan Limbachiya
{"title":"Electron interactions with beryllium and its hydrides","authors":"Ashok Chaudhari ,&nbsp;Harshad Bhutadia ,&nbsp;Smruti Parikh ,&nbsp;Minaxi Vinodkumar ,&nbsp;Chetan Limbachiya","doi":"10.1016/j.ijms.2024.117269","DOIUrl":null,"url":null,"abstract":"<div><p>In present study of electron driven inelastic processes<strong>,</strong> we report calculated probabilities of inelastic events (including total inelastic and ionizations) occurrence by quantifying the cross sections, <span><math><mrow><msub><mi>Q</mi><mrow><mi>i</mi><mi>n</mi><mi>e</mi><mi>l</mi></mrow></msub></mrow></math></span> and <span><math><mrow><msub><mi>Q</mi><mrow><mi>i</mi><mi>o</mi><mi>n</mi></mrow></msub></mrow></math></span> for beryllium (Be) and beryllium hydrides viz. BeH, BeH<sub>2</sub>, Be<sub>2</sub>H<sub>2</sub> and Be<sub>2</sub>H<sub>4</sub> from the molecular ionization threshold to 5 keV. The Spherical Complex Optical Potential (SCOP) to compute <span><math><mrow><msub><mi>Q</mi><mrow><mi>i</mi><mi>n</mi><mi>e</mi><mi>l</mi></mrow></msub></mrow></math></span> has been employed and <span><math><mrow><msub><mi>Q</mi><mrow><mi>i</mi><mi>o</mi><mi>n</mi></mrow></msub></mrow></math></span> is extracted using Complex Scattering Potential –ionization contribution (CSP-ic) approximation. Owing to the toxic character of beryllium compounds we do not find any experimental work for these molecules. In paucity of the experimental data, present work is important and will fill the void of the data needed for particular in plasma physics, aero science, astrophysics and chemical analysis. This study is the maiden report of <span><math><mrow><msub><mi>Q</mi><mrow><mi>i</mi><mi>n</mi><mi>e</mi><mi>l</mi></mrow></msub></mrow></math></span> for all of these important targets.</p></div>","PeriodicalId":338,"journal":{"name":"International Journal of Mass Spectrometry","volume":"502 ","pages":"Article 117269"},"PeriodicalIF":1.6000,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387380624000800","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
引用次数: 0

Abstract

In present study of electron driven inelastic processes, we report calculated probabilities of inelastic events (including total inelastic and ionizations) occurrence by quantifying the cross sections, Qinel and Qion for beryllium (Be) and beryllium hydrides viz. BeH, BeH2, Be2H2 and Be2H4 from the molecular ionization threshold to 5 keV. The Spherical Complex Optical Potential (SCOP) to compute Qinel has been employed and Qion is extracted using Complex Scattering Potential –ionization contribution (CSP-ic) approximation. Owing to the toxic character of beryllium compounds we do not find any experimental work for these molecules. In paucity of the experimental data, present work is important and will fill the void of the data needed for particular in plasma physics, aero science, astrophysics and chemical analysis. This study is the maiden report of Qinel for all of these important targets.

Abstract Image

铍及其氢化物的电子相互作用
在本项关于电子驱动非弹性过程的研究中,我们通过量化铍(Be)和铍氢化物(即 BeH、BeH2、Be2H2 和 Be2H4)从分子电离阈值到 5 keV 的横截面、Qinel 和 Qion,报告了非弹性事件(包括总非弹性和电离)发生的概率计算结果。计算 Qinel 时使用了球形复光学势 (SCOP),Qion 则使用复散射势-电离贡献 (CSP-ic) 近似法提取。由于铍化合物的毒性,我们没有发现任何关于这些分子的实验研究。在实验数据匮乏的情况下,本研究具有重要意义,它将填补等离子物理学、航空科学、天体物理学和化学分析等领域所需的数据空白。本研究是 Qinel 针对所有这些重要目标的首次报告。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
CiteScore
3.60
自引率
5.60%
发文量
145
审稿时长
71 days
期刊介绍: The journal invites papers that advance the field of mass spectrometry by exploring fundamental aspects of ion processes using both the experimental and theoretical approaches, developing new instrumentation and experimental strategies for chemical analysis using mass spectrometry, developing new computational strategies for data interpretation and integration, reporting new applications of mass spectrometry and hyphenated techniques in biology, chemistry, geology, and physics. Papers, in which standard mass spectrometry techniques are used for analysis will not be considered. IJMS publishes full-length articles, short communications, reviews, and feature articles including young scientist features.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信