Copolymers of 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate with methyl methacrylate and their microstructure

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Mendeleev Communications Pub Date : 2024-05-01 DOI:10.1016/j.mencom.2024.04.007

Adel I. Gaysin, Tatyana A. Vakhonina, Ekaterina O. Yakovleva, Marina Yu. Balakina, Oleg G. Sinyashin

引用次数: 0

Abstract

A precursor for the production of azo chromophores, viz. 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate, was prepared and characterized. Its copolymerization with methyl methacrylate was carried out and the copolymerization constants were determined: for 2-hydroxy-3-(N-methyl-N-phenylamino) propyl methacrylate, r₁ = 0.50; for methyl methacrylate, r₂ = 0.93. The average block lengths of monomers of the same type depending on the composition of the copolymer were estimated.

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2-羟基-3-(N-甲基-N-苯基氨基)丙基甲基丙烯酸酯与甲基丙烯酸甲酯的共聚物及其微观结构

制备并鉴定了一种用于生产偶氮发色团的前体，即 2-羟基-3-（N-甲基-N-苯基氨基）丙基甲基丙烯酸酯。对其与甲基丙烯酸甲酯进行了共聚，并测定了共聚常数：对于 2-羟基-3-（N-甲基-N-苯基氨基）丙基甲基丙烯酸酯，r1 = 0.50；对于甲基丙烯酸甲酯，r2 = 0.93。根据共聚物的组成，对同类单体的平均嵌段长度进行了估算。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Mendeleev Communications 化学-化学综合

CiteScore

3.00

自引率

21.10%

发文量

226

审稿时长

4-8 weeks

期刊介绍： Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.