Preparation of activated carbon composite electrode from sugarcane bagasse and its application on energy storage devices

IF 2.5 4区 材料科学 Q2 CHEMISTRY, APPLIED
Hsin Her Yu, Chia-Hua Lin, Jung-Ling Chang, Min-Yu Chen, Ci-Pei Lin, Hsu-Feng Lee
{"title":"Preparation of activated carbon composite electrode from sugarcane bagasse and its application on energy storage devices","authors":"Hsin Her Yu,&nbsp;Chia-Hua Lin,&nbsp;Jung-Ling Chang,&nbsp;Min-Yu Chen,&nbsp;Ci-Pei Lin,&nbsp;Hsu-Feng Lee","doi":"10.1007/s10934-024-01644-2","DOIUrl":null,"url":null,"abstract":"<div><p>Based on sustainable resource recycling, we utilize physical and chemical activation to modify sugarcane bagasse into activated carbon materials with a porous structure. The activated carbon modified with KOH-KNO<sub>3</sub> exhibits a high specific surface area and excellent specific capacitance, and the fabricated composite electrode demonstrates superior electrical conductivity of 57mS/cm. Subsequently, a supercapacitor containing an electrode, gel electrolyte, and separator is assembled in a sandwich structure. It achieves a specific capacitance of 262.4 F/g, an energy density of 17.9 Wh/kg, and a power density of 2021 W/kg at a scanning rate of 0.02 V/s. Furthermore, the supercapacitor demonstrates excellent cycle stability since it can maintain 98.38% of its initial capacitance after 20,000 cycles of charge and discharge under a constant current. In addition, the KOH-KNO<sub>3</sub>-modified activated carbon composite electrode exhibited superior electrochemical performance after we compared it to other carbon electrode supercapacitors derived from agricultural wastes.</p></div>","PeriodicalId":660,"journal":{"name":"Journal of Porous Materials","volume":"31 5","pages":"1839 - 1852"},"PeriodicalIF":2.5000,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Porous Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10934-024-01644-2","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0

Abstract

Based on sustainable resource recycling, we utilize physical and chemical activation to modify sugarcane bagasse into activated carbon materials with a porous structure. The activated carbon modified with KOH-KNO3 exhibits a high specific surface area and excellent specific capacitance, and the fabricated composite electrode demonstrates superior electrical conductivity of 57mS/cm. Subsequently, a supercapacitor containing an electrode, gel electrolyte, and separator is assembled in a sandwich structure. It achieves a specific capacitance of 262.4 F/g, an energy density of 17.9 Wh/kg, and a power density of 2021 W/kg at a scanning rate of 0.02 V/s. Furthermore, the supercapacitor demonstrates excellent cycle stability since it can maintain 98.38% of its initial capacitance after 20,000 cycles of charge and discharge under a constant current. In addition, the KOH-KNO3-modified activated carbon composite electrode exhibited superior electrochemical performance after we compared it to other carbon electrode supercapacitors derived from agricultural wastes.

Abstract Image

Abstract Image

利用甘蔗渣制备活性炭复合电极及其在储能设备上的应用
在可持续资源循环利用的基础上,我们利用物理和化学活化技术将甘蔗渣改性为具有多孔结构的活性炭材料。用 KOH-KNO3 改性的活性炭具有高比表面积和优异的比电容,制成的复合电极具有 57mS/cm 的优异导电性。随后,一个包含电极、凝胶电解质和隔膜的超级电容器被组装成三明治结构。在 0.02 V/s 的扫描速率下,它的比电容达到 262.4 F/g,能量密度为 17.9 Wh/kg,功率密度为 2021 W/kg。此外,该超级电容器还具有出色的循环稳定性,在恒定电流下进行 20,000 次充放电循环后,仍能保持其初始电容的 98.38%。此外,我们将 KOH-KNO3 改性活性碳复合电极与其他从农业废弃物中提取的碳电极超级电容器进行比较后发现,该电极的电化学性能更优越。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of Porous Materials
Journal of Porous Materials 工程技术-材料科学:综合
CiteScore
4.80
自引率
7.70%
发文量
203
审稿时长
2.6 months
期刊介绍: The Journal of Porous Materials is an interdisciplinary and international periodical devoted to all types of porous materials. Its aim is the rapid publication of high quality, peer-reviewed papers focused on the synthesis, processing, characterization and property evaluation of all porous materials. The objective is to establish a unique journal that will serve as a principal means of communication for the growing interdisciplinary field of porous materials. Porous materials include microporous materials with 50 nm pores. Examples of microporous materials are natural and synthetic molecular sieves, cationic and anionic clays, pillared clays, tobermorites, pillared Zr and Ti phosphates, spherosilicates, carbons, porous polymers, xerogels, etc. Mesoporous materials include synthetic molecular sieves, xerogels, aerogels, glasses, glass ceramics, porous polymers, etc.; while macroporous materials include ceramics, glass ceramics, porous polymers, aerogels, cement, etc. The porous materials can be crystalline, semicrystalline or noncrystalline, or combinations thereof. They can also be either organic, inorganic, or their composites. The overall objective of the journal is the establishment of one main forum covering the basic and applied aspects of all porous materials.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信