Zhen Xue, Kuanjun Fang, Lujian Shi, Xue Li, Baohua Feng, Zhangcao Xiao, Wei Bao, Lixin Du, Yawei Song
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引用次数: 0
Abstract
As a good alternative to natural fibers and petroleum-derived fibers, Lyocell fibers draw increasing interests owing to its advantages of sustainable forest source, low carbon emission, high strength and comfort. However, Lyocell exhibits significant fibrillation behavior under friction, which seriously reduce product quality and limit its further development. Herein, dual crosslinking networks were innovatively constructed in Lyocell cellulose structure to enhance the interaction of cellulose macromolecular chains. Bifunctional reactive dyes were loaded in the inner part of Lyocell fiber to form a primary crosslinking network. Then, the cellulose interaction in Lyocell skin layer was further enhanced after the coating by cationic waterborne polyurethane. The mechanism was determined and results showed that durable dual crosslinking networks were formed in Lyocell cellulose structure. From scanning electron microscope (SEM) observation, fibrillation behavior of Lyocell fibers was effectively prevented by dual crosslinking networks. Meanwhile, the durability was evaluated, showing that the treated fabric maintained good anti-fibrillation performance after washing for 50 times. Furthermore, the interaction of dyes and fibers was also enhanced by the cationic polymer via electrostatic attraction force, realizing high dye utilization efficiency. Therefore, the method exhibits great potential in promoting the application of Lyocell fibers in greener textile.
期刊介绍:
Cellulose is an international journal devoted to the dissemination of research and scientific and technological progress in the field of cellulose and related naturally occurring polymers. The journal is concerned with the pure and applied science of cellulose and related materials, and also with the development of relevant new technologies. This includes the chemistry, biochemistry, physics and materials science of cellulose and its sources, including wood and other biomass resources, and their derivatives. Coverage extends to the conversion of these polymers and resources into manufactured goods, such as pulp, paper, textiles, and manufactured as well natural fibers, and to the chemistry of materials used in their processing. Cellulose publishes review articles, research papers, and technical notes.