Technological Properties of Clay Raw Materials of the Northwest Orenburg Region

IF 0.6 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS
O. P. Kushnareva, O. N. Kanygina, D. K. Chetverikova
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Abstract

The chemical composition and technological properties of clay polymineral raw materials from the northwest of the Orenburg region were studied. On the basis of the chemical composition, the raw material can be attributed to semi-acidic sanded clays with a high content of coloring iron oxide Fe2O3 (4.83%). The dependences of the viscosity of clay suspensions at sufficiently high concentrations (up to 0.16 vol.%) are defined; the linear character is confirmed by a high correlation coefficient and plasticity of the raw materials, studied in two ways — by pressing the balls and bending the bands. This indicates a high content of sand. Sintering in the temperature range from 600 to 1000°C did not occur, resulting in the sample cracking. Macroparameters of sintering and color parameters of samples under high temperature, as well as the phase composition, suggest unsatisfactory mechanical characteristics of ceramics from the studied raw materials. Low sorption properties of mineral raw materials with respect to copper and lead ions were established. It is shown that the use of this raw material in the ceramic industry is impractical. It is recommended that the materials be used in road construction, landscaping, and as thinning additives to reduce the plasticity and shrinkage of clays during drying and firing.

Abstract Image

奥伦堡西北地区粘土原料的技术特性
对奥伦堡州西北部粘土多矿物原料的化学成分和技术特性进行了研究。从化学成分来看,原材料属于半酸性砂质粘土,其中有色氧化铁 Fe2O3 含量较高(4.83%)。粘土悬浮液的粘度在足够高的浓度(高达 0.16 vol.%)下的相关性已经确定;原料的高相关系数和可塑性证实了其线性特征,可通过压球和弯曲带两种方式进行研究。这表明砂的含量很高。在 600 至 1000°C 的温度范围内没有发生烧结,导致样品开裂。高温下烧结的宏观参数和样品的颜色参数以及相组成表明,所研究原料的陶瓷机械特性并不令人满意。已确定矿物原料对铜和铅离子的吸附特性较低。这表明,在陶瓷工业中使用这种原材料是不切实际的。建议将这些材料用于道路建设、景观美化,以及用作稀释添加剂,以降低粘土在干燥和烧制过程中的可塑性和收缩性。
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来源期刊
Glass and Ceramics
Glass and Ceramics 工程技术-材料科学:硅酸盐
CiteScore
1.00
自引率
16.70%
发文量
85
审稿时长
6-12 weeks
期刊介绍: Glass and Ceramics reports on advances in basic and applied research and plant production techniques in glass and ceramics. The journal''s broad coverage includes developments in the areas of silicate chemistry, mineralogy and metallurgy, crystal chemistry, solid state reactions, raw materials, phase equilibria, reaction kinetics, physicochemical analysis, physics of dielectrics, and refractories, among others.
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