Solvent effects on carbohydrate transformation: insights into chemical pathway modulation

IF 9.3 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Green Chemistry Pub Date : 2024-06-17 DOI:10.1039/d3gc04901a

Yaxu Sun , Zhihan Tong , Yanyan Yu , Wanke Cheng , Yilin Li , Suqing Zeng , Yuhan Lou , Yongzhuang Liu , Qinqin Xia , Haipeng Yu

引用次数: 0

Abstract

Carbohydrate utilization is a crucial aspect of sustainable resource development and offers a promising avenue for replacing fossil fuels. In carbohydrate reaction systems, solvent effects influence the interactions among carbohydrates, catalysts, and solvents. These can affect the reaction trajectory and selectivity, making them a crucial tool for cost-effectively regulating reactions. This review summarizes the primary types of carbohydrate chemical transformation and commonly used solvent systems, providing an overview of solvent effects in these reactions and an insight into solvent effects from a microscopic perspective. Additionally, it provides insights into the current state of solvent engineering and the challenges limiting the development of solvent-based carbohydrate transformation systems.

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溶剂对碳水化合物转化的影响：对化学途径调节的见解

碳水化合物的利用是可持续资源开发的一个重要方面，并为替代化石燃料提供了一条前景广阔的途径。在碳水化合物反应体系中，溶剂效应会影响碳水化合物、催化剂和溶剂之间的相互作用。这些效应会影响反应轨迹和选择性，使其成为经济有效地调节反应的重要工具。本综述总结了碳水化合物化学转化的主要类型和常用溶剂系统，概述了这些反应中的溶剂效应，并从微观角度深入分析了溶剂效应。此外，它还深入探讨了溶剂工程的现状以及限制基于溶剂的碳水化合物转化体系发展的挑战。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Green Chemistry 化学-化学综合

CiteScore

16.10

自引率

7.10%

发文量

677

审稿时长

1.4 months

期刊介绍： Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.