Structural Regulations of Layered Borates: From Centric Layers to Chiral Porous Layers

Precision Chemistry Pub Date : 2024-05-19 DOI:10.1021/prechem.4c00010

Chong-An Chen, and , Guo-Yu Yang*,

{"title":"Structural Regulations of Layered Borates: From Centric Layers to Chiral Porous Layers","authors":"Chong-An Chen,  and , Guo-Yu Yang*, ","doi":"10.1021/prechem.4c00010","DOIUrl":null,"url":null,"abstract":"Three pentaborates were made by precise structural regulations under hydrothermal conditions, namely, K2Cs[B5O8(OH)]·0.5CO3 (1), KNa4Cs[B5O8(OH)]2·2OH (2), and NaBa[B5O8.5(OH)] (3). Compound 1 features the typical 2D layers constructed from the four-connected B5O10(OH) clusters. By adjustment of the reactants and pH values of the systems to remove interlayered CO32– groups, the centric layers in 1 were transformed to the chiral layers of 2. By further adjusting cationic templates based on host–guest charge matching, the B5O10(OH) cluster unit was transformed to B5O11(OH), which built the chiral porous layers of 3. The chiral compounds 2 and 3 exhibit moderate second harmonic generation (SHG) responses of 1.1 and 1.7 times that of KDP (KH2PO4). The structural regulations actualize the evolutions on both structural symmetries and dimensions.","PeriodicalId":29793,"journal":{"name":"Precision Chemistry","volume":"2 6","pages":"256–262"},"PeriodicalIF":0.0000,"publicationDate":"2024-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/prechem.4c00010","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Precision Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://pubs.acs.org/doi/10.1021/prechem.4c00010","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

Abstract

Three pentaborates were made by precise structural regulations under hydrothermal conditions, namely, K₂Cs[B₅O₈(OH)]·0.5CO₃ (1), KNa₄Cs[B₅O₈(OH)]₂·2OH (2), and NaBa[B₅O_8.5(OH)] (3). Compound 1 features the typical 2D layers constructed from the four-connected B₅O₁₀(OH) clusters. By adjustment of the reactants and pH values of the systems to remove interlayered CO₃^2– groups, the centric layers in 1 were transformed to the chiral layers of 2. By further adjusting cationic templates based on host–guest charge matching, the B₅O₁₀(OH) cluster unit was transformed to B₅O₁₁(OH), which built the chiral porous layers of 3. The chiral compounds 2 and 3 exhibit moderate second harmonic generation (SHG) responses of 1.1 and 1.7 times that of KDP (KH₂PO₄). The structural regulations actualize the evolutions on both structural symmetries and dimensions.

Abstract Image

查看原文本刊更多论文

层状硼酸盐的结构规律：从中心层到手性多孔层

在水热条件下通过精确的结构调整制得了三种五硼酸盐，即 K2Cs[B5O8(OH)]-0.5CO3 (1)、KNa4Cs[B5O8(OH)]2-2OH (2) 和 NaBa[B5O8.5(OH)] (3)。化合物 1 具有典型的二维层，由四个相连的 B5O10(OH) 簇构建而成。通过调整反应物和体系的 pH 值以去除夹层的 CO32- 基团，1 中的中心层转变为 2 中的手性层；通过进一步调整基于主客电荷匹配的阳离子模板，B5O10(OH) 团簇单元转变为 B5O11(OH)，从而构建了 3 中的手性多孔层。手性化合物 2 和 3 显示出适度的二次谐波发生（SHG）响应，分别是 KDP (KH2PO4) 的 1.1 倍和 1.7 倍。结构规则实现了结构对称性和尺寸的演变。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Precision Chemistry 精密化学技术-

CiteScore

0.80

自引率

0.00%

发文量

期刊介绍： Chemical research focused on precision enables more controllable predictable and accurate outcomes which in turn drive innovation in measurement science sustainable materials information materials personalized medicines energy environmental science and countless other fields requiring chemical insights.Precision Chemistry provides a unique and highly focused publishing venue for fundamental applied and interdisciplinary research aiming to achieve precision calculation design synthesis manipulation measurement and manufacturing. It is committed to bringing together researchers from across the chemical sciences and the related scientific areas to showcase original research and critical reviews of exceptional quality significance and interest to the broad chemistry and scientific community.