Development of a Biodegradable Cassava Starch Biofilm based on a Combination of Plasticizers with Bio‐SiO2 Extracted from Sugarcane Leaves

Piyanan Boonphayak, Nutradee Muenyong, Rattanaporn Chinchao, Sirikarn Khansumled
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Abstract

This study prepares biodegradable biofilms for packaging applications from biomass to help reduce plastic waste while also adding value to biomass. Furthermore, the effects of plasticization with 30 wt% plasticizer (relative to the mass of cassava starch) by glycerol (G), sorbitol (S), and a mixture of glycerol and sorbitol (GS) plasticizers are investigated, and the effects of bio‐SiO2 particles extracted from sugarcane leave via the sol–gel method are evaluated in terms of the mechanical and biodegradability properties of the cassava starch‐based biofilms. Biofilms used for packing applications must be insoluble and exhibit good elongation properties. In this context, the results indicate that the GS mixture produces a biofilm that exhibits these desirable properties. Thus, cassava starch‐based biofilms are prepared using GS and varying concentrations of the bio‐SiO2 particles (i.e., 0, 0.5, 1, and 1.5 wt%). The films containing bio‐SiO2 exhibit significantly lower water solubilities and moisture contents than the corresponding bio‐SiO2‐free films. Additionally, the inclusion of bio‐SiO2 particles increases the water resistance properties of the biofilms. Overall, the results suggest that cassava starch films prepared using a mixture of plasticizers and reinforced with bio‐SiO2 particles can be considered a safe material for application in biodegradable food packaging.
基于增塑剂与从甘蔗叶中提取的生物二氧化硅的组合开发可生物降解的木薯淀粉生物膜
本研究利用生物质制备了可生物降解的生物膜,用于包装应用,以帮助减少塑料垃圾,同时增加生物质的价值。此外,还研究了甘油(G)、山梨醇(S)以及甘油和山梨醇混合物(GS)增塑剂增塑 30 wt%(相对于木薯淀粉的质量)的效果,并评估了通过溶胶-凝胶法从甘蔗叶中提取的生物二氧化硅颗粒对木薯淀粉基生物膜的机械和生物降解性能的影响。用于包装的生物膜必须具有不溶性和良好的伸长特性。在这种情况下,结果表明 GS 混合物产生的生物膜具有这些理想的特性。因此,使用 GS 和不同浓度的生物二氧化硅颗粒(即 0、0.5、1 和 1.5 wt%)制备了基于木薯淀粉的生物膜。与不含生物二氧化硅的薄膜相比,含有生物二氧化硅的薄膜的水溶性和含水量明显较低。此外,加入生物二氧化硅颗粒还能提高生物膜的耐水性能。总之,研究结果表明,使用增塑剂混合物制备并用生物二氧化硅颗粒增强的木薯淀粉薄膜是一种安全的材料,可应用于生物降解食品包装。
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