{"title":"Restraining Lattice Oxygen Escape by Bioinspired Antioxidant Enables Thermal Runaway Prevention in Ni−Rich Cathode Based Lithium−Ion Batteries","authors":"Yuanke Wu, Ziqi Zeng, Mengchuang Liu, Chuyue Cai, Sheng Lei, Han Zhang, Shijie Cheng, Jia Xie","doi":"10.1002/aenm.202401037","DOIUrl":null,"url":null,"abstract":"<p>Ni−rich cathodes are hopeful materials for advanced lithium−ion batteries (LIBs) due to high capacity. Nonetheless, the chemical crosstalk triggered by reactive oxygen (O<sup>*</sup>) represents a critical factor in thermal runaway (TR). Currently, there are few effective means to prevent this parasitic reaction. Here, inspired by the O<sup>*</sup> scavenging effect of β−carotene in living organisms, it is innovatively identified that β−carotene can impede TR by restraining the escape of O<sup>*</sup> during the thermal decomposition of nickel−rich cathodes. Using LiNi<sub>0.6</sub>Co<sub>0.2</sub>Mn<sub>0.2</sub>O<sub>2</sub> as model and extending to higher nickel content cathodes (LiNi<sub>0.8</sub>Co<sub>0.1</sub>Mn<sub>0.1</sub>O<sub>2</sub>, LiNi<sub>0.9</sub>Co<sub>0.05</sub>Mn<sub>0.05</sub>O<sub>2</sub>), it is demonstrated that β−carotene can undergo an in situ oxygen copolymerization reaction to trapping O<sup>*</sup>, thereby attenuating chemical crosstalk. Additionally, the generated oxygen copolymer can also adjust band center of the O 2p orbitals of delithiated cathode, alleviating the charge compensation behavior of oxygen anions, and thus delaying the phase transition of charged LiNi<sub>0.8</sub>Co<sub>0.1</sub>Mn<sub>0.1</sub>O<sub>2</sub>. As a result, the TR trigger temperature of NCM811∣Graphite pouch cell is increased from 131.0 to 195.0 °C and maximum temperature is reduced from 657.8 to 412.4 °C. This work introduces a new and simple strategy for designing functional additives to block TR, offering a promising avenue for advancing the safety of LIBs.</p>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":null,"pages":null},"PeriodicalIF":24.4000,"publicationDate":"2024-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Energy Materials","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aenm.202401037","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Ni−rich cathodes are hopeful materials for advanced lithium−ion batteries (LIBs) due to high capacity. Nonetheless, the chemical crosstalk triggered by reactive oxygen (O*) represents a critical factor in thermal runaway (TR). Currently, there are few effective means to prevent this parasitic reaction. Here, inspired by the O* scavenging effect of β−carotene in living organisms, it is innovatively identified that β−carotene can impede TR by restraining the escape of O* during the thermal decomposition of nickel−rich cathodes. Using LiNi0.6Co0.2Mn0.2O2 as model and extending to higher nickel content cathodes (LiNi0.8Co0.1Mn0.1O2, LiNi0.9Co0.05Mn0.05O2), it is demonstrated that β−carotene can undergo an in situ oxygen copolymerization reaction to trapping O*, thereby attenuating chemical crosstalk. Additionally, the generated oxygen copolymer can also adjust band center of the O 2p orbitals of delithiated cathode, alleviating the charge compensation behavior of oxygen anions, and thus delaying the phase transition of charged LiNi0.8Co0.1Mn0.1O2. As a result, the TR trigger temperature of NCM811∣Graphite pouch cell is increased from 131.0 to 195.0 °C and maximum temperature is reduced from 657.8 to 412.4 °C. This work introduces a new and simple strategy for designing functional additives to block TR, offering a promising avenue for advancing the safety of LIBs.
期刊介绍:
Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small.
With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics.
The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.