{"title":"Photocatalysis toward Microplastics Conversion: A Critical Review","authors":"Ganghua Zhou, Hangmin Xu, Hao Song, Jianjian Yi, Xiaozhi Wang*, Zupeng Chen* and Xingwang Zhu*, ","doi":"10.1021/acscatal.4c01449","DOIUrl":null,"url":null,"abstract":"<p >Microplastics (MPs, particle size < 5 mm) have become increasingly ubiquitous on Earth due to the cleavage and degradation of the heavy use of plastics. MPs have recently been reported to be detected in human blood, alveoli, breast milk, embryos, and other organs, raising concerns about their environmental risks. Photocatalysis has been identified as a potential means for MPs conversion, which utilizes solar energy to stimulate a semiconductor photocatalyst. However, the study of photocatalytic conversion of MPs is still in the incubation period. This review overviews the current state-of-the-art technologies for MPs conversion. Then, the fundamental principles, challenges, analytical techniques, and evaluation indexes of photocatalytic MPs reforming are highlighted. We have systematically summarized the recent advances in the photocatalytic conversion of MPs and identified the key factors influencing photocatalytic performance. Finally, we propose some perspectives for developing efficient photocatalytic systems for reforming MPs. This review will provide a guideline for developing and applying photocatalytic technology for reforming MPs, which will significantly contribute to developing this emerging research field.</p>","PeriodicalId":9,"journal":{"name":"ACS Catalysis ","volume":null,"pages":null},"PeriodicalIF":11.3000,"publicationDate":"2024-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Catalysis ","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acscatal.4c01449","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Microplastics (MPs, particle size < 5 mm) have become increasingly ubiquitous on Earth due to the cleavage and degradation of the heavy use of plastics. MPs have recently been reported to be detected in human blood, alveoli, breast milk, embryos, and other organs, raising concerns about their environmental risks. Photocatalysis has been identified as a potential means for MPs conversion, which utilizes solar energy to stimulate a semiconductor photocatalyst. However, the study of photocatalytic conversion of MPs is still in the incubation period. This review overviews the current state-of-the-art technologies for MPs conversion. Then, the fundamental principles, challenges, analytical techniques, and evaluation indexes of photocatalytic MPs reforming are highlighted. We have systematically summarized the recent advances in the photocatalytic conversion of MPs and identified the key factors influencing photocatalytic performance. Finally, we propose some perspectives for developing efficient photocatalytic systems for reforming MPs. This review will provide a guideline for developing and applying photocatalytic technology for reforming MPs, which will significantly contribute to developing this emerging research field.
期刊介绍:
ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels.
The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.