Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2024-05-16 DOI:10.1134/S1070328423601309

E. P. Ivakhnenko, Yu. G. Vitkovskaya, N. I. Merezhko, P. A. Knyazev, G. S. Borodkin, K. A. Lysenko, V. I. Minkin

引用次数: 0

Abstract

The Сd(II) complexes with redox amphoteric 2,6-di-(tert-butyl)-4-((2-hydroxyphenyl)imino)cyclohexa-2,5-dienone ligands L¹ and L² (adducts I, II, and III) are synthesized. The structures of coordinated complexes I, II, and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (II) and 1838310 (III)) and confirmed by the ¹Н, ¹³С, and ¹¹³Cd NMR spectroscopy (for complexes I and III) and IR spectroscopy data.

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氧化还原活性靛酚配体的镉(II)配合物：合成与结构

摘要合成了氧化还原两性 2,6-二(叔丁基)-4-((2-羟基苯基)亚氨基)环己-2,5-二烯酮配体 L1 和 L2 的Сd(II)配合物（加合物 I、II 和 III）。配位络合物 I、II 和 III 的结构由 X 射线衍射 (XRD) 确定（CIF 文件 CCDC 编号：1838319 (II) 和 1838310 (III)），并由 1Н、13С 和 113Cd NMR 光谱（络合物 I 和 III）和红外光谱数据证实。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.