Nitramino-polymer with ether bridges and 1,2,3-triazole subunits incorporated into the polymer chain

Pavel S. Gribov , Natalia N. Il'icheva , Natalia N. Kondakova , Evgenia R. Stepanova , Anatoly P. Denisyuk , Vladimir A. Sizov , Varvara D. Dotsenko , Valery P. Sinditskii , Aleksei B. Sheremetev
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Abstract

The creation of novel energetic polymers for future advanced solid composite propellants and gunpowder is an urgent area of modern research. A simple and effective waste-free cycloaddition reaction between dialkyne and diazide comonomers, both bearing nitramine groups, for the synthesis of an energetic polymer containing explosophoric units in the polymer chain has been described. Neither solvent nor catalyst is required for the production of this polymer, the comonomers used are readily available, and the product does not need any purification, and, importantly, this protocol scales well. The resulting polymer, C1Z1, (C14H22N12O8)n, was comprehensively characterized by spectral and physico-chemical methods. Compatibility with energetic plasticizers (NG, DNDEG, DANPE), thermochemical characteristics and combustion features indicate the prospects of target polymer C1Z1 (density, ρ = 1.484 g/cm3; onset temperatures is 230 °C; positive enthalpy of the formation, ΔHf0 = +636 kJ/kg; burning rate at 10 MPa is 9.5 mm/s) as a binder base for energetic materials. Comparison of C1Z1 with nitrocellulose (NC) and their compositions with plasticizers revealed the advantages of C1Z1.

Abstract Image

聚合物链中含有醚桥和 1,2,3-三唑亚基的硝基聚合物
为未来先进的固体复合推进剂和火药创造新型高能聚合物是现代研究的一个紧迫领域。本文描述了二炔和二叠氮共聚单体(均含硝胺基)之间的一种简单有效的无废环加成反应,用于合成聚合物链中含有爆炸基团的高能聚合物。生产这种聚合物既不需要溶剂也不需要催化剂,使用的共聚物很容易获得,产品不需要任何纯化,重要的是,该方案的规模很好。所得聚合物C1Z1, (C14H22N12O8)n,通过光谱和物理化学方法进行了全面表征。与含能增塑剂(NG、DNDEG、DANPE)的相容性、热化学特性和燃烧特性预示了目标聚合物C1Z1(密度,ρ = 1.484 g/cm3;起始温度为230℃;生成的正焓ΔHf0 = +636 kJ/kg;燃烧速率为9.5 mm/s)作为含能材料的粘结剂。将C1Z1与硝化纤维(NC)进行对比,并与增塑剂进行对比,揭示了C1Z1的优势。
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