Experimental Evaluation of Mechanical Properties, Thermal Analysis, Morphology, Printability, and Shape Memory Performance of the Novel 3D Printed PETG-EVA Blends
IF 4.2 3区 材料科学Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Saeed J. A. Ali, Davood Rahmatabadi, Mostafa Baghani, Majid Baniassadi
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引用次数: 0
Abstract
Polyethylene terephthalate glycol (PETG) is a novel amorphous shape memory polymer with excellent printability for 4D printing. In this article, ethylene-vinyl acetate (EVA) is used as a biocompatible and non-toxic copolymer to improve plasticity and shape memory performance of PETG. PETG-EVA blends are prepared and 3D printed using a melt mixing method and an upgraded fused deposition modeling (FDM) with a pneumatic feeding system. The results of the thermal analysis show that the blends exhibit two tan-delta peaks, each related to their components, and morphology images confirm that they are biphasic and immiscible with good compatibility. The morphology of both EVA10 and EVA30 matrix droplets is observed, with the droplets being larger for EVA30. The use of a pneumatic feeding system, along with the ability to control the output melt flow, results in the best printing ability for EVA30, with minimal microholes between the grids and interlayer cracks. The tensile strength of PETG-EVA blends ranged from 25.38 to 20.14 MPa, with the highest tensile strength achieved for EVA30. The shape memory performance of all three blends is similar; with shape recovery exceeding 90% in 20 s. Blends with higher EVA content exhibited faster shape recovery within the first 10 s.
期刊介绍:
Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, processing and application of advanced polymeric materials, including membranes, sensors, sustainability, composites, fibers, foams, 3D printing, actuators as well as energy and electronic applications.
Macromolecular Materials and Engineering is among the top journals publishing original research in polymer science.
The journal presents strictly peer-reviewed Research Articles, Reviews, Perspectives and Comments.
ISSN: 1438-7492 (print). 1439-2054 (online).
Readership:Polymer scientists, chemists, physicists, materials scientists, engineers
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