A facile treatment of graphite as a reinforcement for Al‐based nanostructured composite

IF 1.6 4区 化学 Q4 CHEMISTRY, PHYSICAL
Elham Bakhshizade, Ali Shokuhfar, Ashkan Zolriasatein, Mehdi Khodaei
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Abstract

Aluminum‐graphite composites find extensive applications in diverse industries, including automotive and aerospace sectors. However, the fabrication of these composites faces a significant challenge due to poor wettability and weak interfacial bonding between graphite and aluminum. This work aims to modify the graphite particles to improve the characteristics of aluminum. In this study, treated graphite (TG) was synthesized using a facile method for the first time. Graphite (G) was mixed with acetone and stirred with a mechanical stirrer at 2000 rpm for 1 h, followed by drying in an electric oven at 80°C for 1 h. Mechanical milling and subsequent hot pressing were employed to manufacture composites with 1, 3, and 5 wt.% of G and TG. The results demonstrated that the addition of G and TG up to 5 wt.% substantially improved the wear rate and coefficient of friction (COF). However, it also resulted in a deterioration of the mechanical properties of aluminum. The TG‐reinforced composites exhibited enhanced mechanical and tribological properties owing to the stronger bonds formed between carbon and aluminum atoms. Notably, the composite with 5‐wt.% G and TG exhibited an 80% and 58% lower COF compared with unreinforced aluminum. Composites containing 1‐wt.% G and TG showed an 11% and 1% reduction in yield strength, respectively. Consequently, the investigated graphite treatment proves to be an effective method for modifying the interfacial bonding and enhancing the comprehensive properties of aluminum. This treatment offers a simple and cost‐effective approach to improve the tribological and mechanical characteristics of aluminum matrix composites.
石墨作为铝基纳米结构复合材料增强剂的简便处理方法
铝-石墨复合材料广泛应用于各行各业,包括汽车和航空航天领域。然而,由于石墨和铝之间的润湿性差、界面结合力弱,这些复合材料的制造面临着巨大挑战。这项工作旨在对石墨颗粒进行改性,以改善铝的特性。本研究首次采用简便方法合成了处理石墨(TG)。将石墨(G)与丙酮混合,用机械搅拌器以 2000 rpm 的转速搅拌 1 小时,然后在 80°C 的电烤箱中干燥 1 小时。结果表明,G 和 TG 的添加量达到 5 wt.%后,磨损率和摩擦系数(COF)都得到了显著改善。然而,这也导致铝的机械性能下降。由于碳原子和铝原子之间形成了更牢固的结合,TG 增强复合材料显示出更强的机械性能和摩擦学性能。值得注意的是,与未增强的铝相比,含有 5 重量百分比 G 和 TG 的复合材料的 COF 分别降低了 80% 和 58%。含有 1 重量百分比 G 和 TG 的复合材料的屈服强度分别降低了 11% 和 1% 。因此,所研究的石墨处理方法被证明是改变铝的界面结合和提高其综合性能的有效方法。这种处理方法为改善铝基复合材料的摩擦学和机械特性提供了一种简单而经济有效的方法。
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来源期刊
Surface and Interface Analysis
Surface and Interface Analysis 化学-物理化学
CiteScore
3.30
自引率
5.90%
发文量
130
审稿时长
4.4 months
期刊介绍: Surface and Interface Analysis is devoted to the publication of papers dealing with the development and application of techniques for the characterization of surfaces, interfaces and thin films. Papers dealing with standardization and quantification are particularly welcome, and also those which deal with the application of these techniques to industrial problems. Papers dealing with the purely theoretical aspects of the technique will also be considered. Review articles will be published; prior consultation with one of the Editors is advised in these cases. Papers must clearly be of scientific value in the field and will be submitted to two independent referees. Contributions must be in English and must not have been published elsewhere, and authors must agree not to communicate the same material for publication to any other journal. Authors are invited to submit their papers for publication to John Watts (UK only), Jose Sanz (Rest of Europe), John T. Grant (all non-European countries, except Japan) or R. Shimizu (Japan only).
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