Kohei Ono, Minki Sung, Yuanshuo Peng, Seung-Jae Ha, Young-Pyo Jeon, Takahashi Ikuya, Hamaguchi Shusaku, Feiyu Kang, Hyeonseok Yi, Joo-Il Park, Koji Nakabayashi, Jin Miyawaki, Seong-Ho Yoon
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引用次数: 0
Abstract
This study involved the heterogenization of a binder pitch (BP) using a small amount of nanocarbon to improve physical properties of the resulting graphite electrode (GE). Heterogenization was carried out by adding 0.5–2.0 wt.% platelet carbon nanofiber (PCNF) or carbon black (CB) to a commercial BP. To evaluate the physical properties of the BPs, we designed a new model graphite electrode (MGE) using needle coke as a filler. The heterogenized binder pitch (HBP) with PCNF or CB clearly increased the coking value by 5–13 wt.% compared to that of the as-received BP. Especially, the model graphite electrodes prepared with HBPs containing 1.0 wt.% PCNF or CB showed significantly improved physical properties compared to the control MGE from the as-received BP. Although the model graphite electrodes prepared with HBPs showed similar properties, they had smaller pore sizes than the control. This indicates that heterogenization of the BP can effectively decrease the pore size in the MGE matrix. Correlating the average pore sizes with the physical properties of the model graphite electrodes showed that, for the same porosity, matrices formed by the HBP with a smaller average pore size can effectively improve the apparent density, tensile strength, and oxidation resistance of the model graphite electrodes.
期刊介绍:
Carbon Letters aims to be a comprehensive journal with complete coverage of carbon materials and carbon-rich molecules. These materials range from, but are not limited to, diamond and graphite through chars, semicokes, mesophase substances, carbon fibers, carbon nanotubes, graphenes, carbon blacks, activated carbons, pyrolytic carbons, glass-like carbons, etc. Papers on the secondary production of new carbon and composite materials from the above mentioned various carbons are within the scope of the journal. Papers on organic substances, including coals, will be considered only if the research has close relation to the resulting carbon materials. Carbon Letters also seeks to keep abreast of new developments in their specialist fields and to unite in finding alternative energy solutions to current issues such as the greenhouse effect and the depletion of the ozone layer. The renewable energy basics, energy storage and conversion, solar energy, wind energy, water energy, nuclear energy, biomass energy, hydrogen production technology, and other clean energy technologies are also within the scope of the journal. Carbon Letters invites original reports of fundamental research in all branches of the theory and practice of carbon science and technology.