Monitoring and Assessment of the Quality of Chlorinated Water in Schools

Water Pub Date : 2024-05-16 DOI:10.3390/w16101415
Vanessa Stein, A. Galvão, A. T. Paulino, Alex Molina Manfredi, Edmar Martendal, Tainara Vieira, W. S. Robazza
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Abstract

All water destined for human consumption must be subjected to disinfection processes via chlorination with the aim of eliminating the risk of the transmission of waterborne diseases. However, the treatment of water using this method leads to the formation of trihalomethanes (THMs), which are toxic compounds that may be ingested, inhaled, or absorbed by the skin, increasing the risk of carcinogenic and mutagenic processes. High trihalomethane concentrations in water may be directly related to physicochemical properties, such as temperature, pH, hardness, and potentially toxic metal concentrations. In this work, physicochemical characterization was performed and water quality was assessed with regard to the presence of trihalomethanes in 17 samples collected from points before and after storage in reservoirs. Atomic absorption spectroscopy to determine potentially toxic metals and the measurement of physicochemical properties demonstrated that all results were in accordance with the standards established by Brazilian legislation. Gas chromatography–mass spectrometry was used to determine levels of trihalomethanes in the water samples (trichloromethane, bromodichloromethane, chlorodibromomethane, and bromoform), which were also in accordance with the limits established by Brazilian legislation. Hierarchical clustering on principal components confirmed changes in the water quality depending on location. This work constitutes a paradigm for future studies on the monitoring of toxic organic compounds in water to avoid health problems in humans and animals.
监测和评估学校氯化水的质量
所有供人类饮用的水都必须经过氯化消毒处理,以消除水传播疾病的风险。然而,使用这种方法处理水会形成三卤甲烷(THMs),这种有毒化合物可能被摄入、吸入或被皮肤吸收,从而增加致癌和致突变的风险。水中高浓度的三卤甲烷可能与温度、pH 值、硬度和潜在有毒金属浓度等物理化学特性直接相关。在这项工作中,对从水库储存前后各点采集的 17 个样本进行了物理化学特征描述,并对水质中是否存在三卤甲烷进行了评估。用原子吸收光谱法测定潜在有毒金属和测量理化特性表明,所有结果均符合巴西法律规定的标准。气相色谱-质谱法用于测定水样中的三卤甲烷(三氯甲烷、溴二氯甲烷、氯二溴甲烷和溴甲烷)含量,结果也符合巴西法律规定的限值。主成分的分层聚类证实了不同地点水质的变化。这项工作为今后监测水中有毒有机化合物以避免人类和动物健康问题的研究提供了范例。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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