High Power Sunlight-Simulated UV-Induced Radical Polymerization: Self-Initiation and Self-Crosslinking

IF 4.2 3区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY

Macromolecular Materials and Engineering Pub Date : 2024-05-16 DOI:10.1002/mame.202470009

Wenqing Yan, Jimena de la Vega, Özen Eroğlu, Lavinia Heisenberg, Deyi Wang

引用次数: 0

Abstract

Front Cover: High power, sunlight-simulated UV light induces radical polymerizations of (meth)acrylate-based monomers. During this process, mono-radicals can be generated through the H-abstraction mechanism, while bi-radicals can arise from photodissociation or oxygen initiation mechanisms. The generated free radicals facilitate self-initiation and self-crosslinking, rendering this technology efficient for synthesizing polymer networks without the need for added initiators or crosslinkers. This is reported by Wenqing Yan and co-workers in article 2399456.

Abstract Image

查看原文本刊更多论文

大功率太阳光模拟紫外线诱导的自由基聚合：自引发和自交联

封面：模拟太阳光的高功率紫外线可诱导以（甲基）丙烯酸酯为基础的单体发生自由基聚合反应。在此过程中，单自由基可通过氢萃取机制产生，而双自由基可通过光解离或氧引发机制产生。生成的自由基可促进自引发和自交联，使该技术无需添加引发剂或交联剂即可高效合成聚合物网络。严文清及其合作者在第 2399456 号文章中对此进行了报道。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Macromolecular Materials and Engineering 工程技术-材料科学：综合

CiteScore

7.30

自引率

5.10%

发文量

328

审稿时长

1.6 months

期刊介绍： Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, processing and application of advanced polymeric materials, including membranes, sensors, sustainability, composites, fibers, foams, 3D printing, actuators as well as energy and electronic applications. Macromolecular Materials and Engineering is among the top journals publishing original research in polymer science. The journal presents strictly peer-reviewed Research Articles, Reviews, Perspectives and Comments. ISSN: 1438-7492 (print). 1439-2054 (online). Readership:Polymer scientists, chemists, physicists, materials scientists, engineers Abstracting and Indexing Information: CAS: Chemical Abstracts Service (ACS) CCR Database (Clarivate Analytics) Chemical Abstracts Service/SciFinder (ACS) Chemistry Server Reaction Center (Clarivate Analytics) ChemWeb (ChemIndustry.com) Chimica Database (Elsevier) COMPENDEX (Elsevier) Current Contents: Physical, Chemical & Earth Sciences (Clarivate Analytics) Directory of Open Access Journals (DOAJ) INSPEC (IET) Journal Citation Reports/Science Edition (Clarivate Analytics) Materials Science & Engineering Database (ProQuest) PASCAL Database (INIST/CNRS) Polymer Library (iSmithers RAPRA) Reaction Citation Index (Clarivate Analytics) Science Citation Index (Clarivate Analytics) Science Citation Index Expanded (Clarivate Analytics) SciTech Premium Collection (ProQuest) SCOPUS (Elsevier) Technology Collection (ProQuest) Web of Science (Clarivate Analytics)