Cyclodextrin Functionalized Ionic Liquids: Synthesis and Application in Analytical Chemistry.

IF 4.2 2区化学 Q1 CHEMISTRY, ANALYTICAL

Critical reviews in analytical chemistry Pub Date : 2024-05-16 DOI:10.1080/10408347.2024.2351815

Ayushi Aggarwal, Harish Kumar Chopra

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Abstract

Cyclodextrins belong to a class of cyclic oligosaccharides composing of α-(1,4) linked glucopyranose subunits having a torus-like macro ring shape. Cyclodextrins based materials find a wide range of applications in separation technology due to their unique property to differentiate between enantiomers, positional isomers and functional groups. Conversely, ionic liquids are the non-molecular compounds composed of different anion and cations with low melting point making them a designer and greener solvents. Because of their fascinating properties, the combined effect of cyclodextrin and ionic liquids as cyclodextrin functionalized ionic liquids (CDILs) have nowadays led to an excellent development for their utilization in the area of analytical chemistry. This review focuses mainly on the synthesis of cyclodextrin functionalized ionic liquids and their application in separation techniques like capillary electrophoresis (CE), high-performance liquid chromatography (HPLC) and gas chromatography (GC). The nature of the interactions between CDILs and analytes have also been highlighted in this review.

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环糊精功能化离子液体：环糊精功能化离子液体：合成及在分析化学中的应用》。

环糊精属于一类环状低聚糖，由具有环状大环形状的α-(1,4) 链葡吡喃糖亚基组成。由于环糊精具有区分对映体、位置异构体和官能团的独特性质，因此它在分离技术领域有着广泛的应用。相反，离子液体是由不同阴阳离子组成的非分子化合物，熔点低，是一种可设计的绿色溶剂。环糊精和离子液体作为环糊精功能化离子液体（CDILs），由于其迷人的特性，如今在分析化学领域的应用得到了很好的发展。本综述主要关注环糊精功能化离子液体的合成及其在毛细管电泳（CE）、高效液相色谱（HPLC）和气相色谱（GC）等分离技术中的应用。本综述还重点介绍了 CDIL 与分析物之间相互作用的性质。

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来源期刊

Critical reviews in analytical chemistry 化学-分析化学

CiteScore

12.00

自引率

4.00%

发文量

137

审稿时长

6 months

期刊介绍： Critical Reviews in Analytical Chemistry continues to be a dependable resource for both the expert and the student by providing in-depth, scholarly, insightful reviews of important topics within the discipline of analytical chemistry and related measurement sciences. The journal exclusively publishes review articles that illuminate the underlying science, that evaluate the field''s status by putting recent developments into proper perspective and context, and that speculate on possible future developments. A limited number of articles are of a "tutorial" format written by experts for scientists seeking introduction or clarification in a new area. This journal serves as a forum for linking various underlying components in broad and interdisciplinary means, while maintaining balance between applied and fundamental research. Topics we are interested in receiving reviews on are the following: · chemical analysis; · instrumentation; · chemometrics; · analytical biochemistry; · medicinal analysis; · forensics; · environmental sciences; · applied physics; · and material science.