Interfacial engineering enables polyaniline-decorated bismuth sulfide nanorods towards ultrafast metal–semiconductor-metal UV-Vis broad spectra photodetector

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES
Anshika Singh, Pratima Chauhan, Arpit Verma, Bal Chandra Yadav
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Abstract

Herein, we reported photoelectric measurements of the polyaniline decorated with bismuth sulfide (Bi2S3/PANI) nanohybrid based metal-semiconductor-metal (MSM) device in the broad electromagnetic (EM) spectrum from ultraviolet (UV) to visible (Vis) range. Bi2S3 nanorods decorated with π-conjugated polymer PANI were utilized as photodetection devices has a wide range of applications in imaging and communication. In such a novel structure, the fast electron transfer at the interface of Bi2S3 and PANI occurs, which enhances the performance of the photodetectors. Current–voltage (IV) characteristics of the MSM photodetector device of Bi2S3/PANI nanohybrid show good ohmic nature. This photodetector device offers the highest external quantum efficiency (EQE) 104% in the UV and visible regions. It also shows the greatest detectivity of the order 1014 Jones. The photoresponsivity of the Bi2S3/PANI nanohybrid photodetector device shows 270 mAW−1 in UV region and 1270 mAW−1 in visible region at only 1 V with the minimum optical signal of 50 µWcm−2. The highest photoresponsivity of the Bi2S3/PANI nanohybrid photodetector offers 26,760 mAW−1 and 13,250 mAW−1 for the UV and visible spectra, respectively. The higher values of the LDR are 64.31 dB and 58.21 dB in the UV and visible regions, respectively, at 100 V with the lowest illumination intensity. The minimum value of NEP found in the order of 10−9 W which is the lowest value, suggests that the nanohybrid material is perfect for low-intensity photon signals. This work provides simple and effective method for the preparation of MSM photodetector technology exhibits a magnificent performance in the UV-to-Vis region.

Abstract Image

界面工程使聚苯胺装饰的硫化铋纳米棒实现超快金属-半导体-金属紫外-可见宽光谱光电探测器
在此,我们报告了基于金属-半导体-金属(MSM)器件的聚苯胺与硫化铋(Bi2S3/PANI)纳米杂化装饰在从紫外线(UV)到可见光(Vis)的宽电磁(EM)光谱范围内的光电测量结果。用 π 共轭聚合物 PANI 装饰的 Bi2S3 纳米棒被用作光检测器件,在成像和通信领域有着广泛的应用。在这种新颖的结构中,Bi2S3 和 PANI 的界面发生了快速电子转移,从而提高了光电探测器的性能。Bi2S3/PANI 纳米杂化 MSM 光电探测器器件的电流-电压(I-V)特性显示出良好的欧姆特性。这种光电探测器在紫外和可见光区域的外部量子效率(EQE)最高,达到 104%。它还显示出 1014 琼斯数量级的最大检测率。Bi2S3/PANI 纳米杂化光电探测器器件的光致发光率在紫外区为 270 mAW-1,在可见光区为 1270 mAW-1,最低光信号为 50 µWcm-2,电压仅为 1 V。Bi2S3/PANI 纳米杂化光电探测器在紫外和可见光谱的最高光致发光率分别为 26,760 mAW-1 和 13,250 mAW-1。在 100 V 的最低照明强度下,紫外和可见光区域的 LDR 较高值分别为 64.31 dB 和 58.21 dB。NEP 的最小值为 10-9 W,这是最低值,表明纳米杂化材料非常适合低强度光子信号。这项工作为制备 MSM 光电探测器技术提供了简单而有效的方法,该技术在紫外-可见光区域表现出卓越的性能。
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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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