3D Coordination Polymers with N-Heterocyclic Ga(I) Moieties

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2024-05-08 DOI:10.1134/S1070328423601127

T. S. Koptseva, E. V. Baranov, I. L. Fedushkin

引用次数: 0

Abstract

The reactions of bimetallic acenaphthene-1,2-diimine complex [(Dpp-bian-GaCr(CO)₅]₂-[Na(Thf)₂]₂ (I) (Dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with 4,4'-bipyridine (4,4'-Bipy) and 1,3-bis(4-pyridyl)propane (Bpp) in THF gave 3D coordination polymers [{(Dpp-bian)GaCr(CO)₅}{Na(4,4'-Bipy)₃}]_n (II) and [(Dpp-bian)GaCr(CO)₄Na(Et₂O)(Bpp)_1,5]_n (III), respectively. Compounds II and III were characterized by elemental analysis and NMR and IR spectroscopy. The molecular structure of II was established by X-ray diffraction (CCDC no. 2278024).

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含 N-杂环 Ga(I) 分子的三维配位聚合物

摘要双金属苊-1,2-二亚胺配合物[(Dpp-bian-GaCr(CO)5]2-[Na(Thf)2]2 (I)（Dpp-bian = 1,2-双[(2,6-二异丙基苯基)亚氨基]苊）与 4,4'-联吡啶（4、4'-联吡）和 1,3-双（4-吡啶基）丙烷（Bpp）在 THF 中的反应分别得到了三维配位聚合物[{(Dpp-bian)GaCr(CO)5}{Na(4,4'-联吡)3}]n（II）和[(Dpp-bian)GaCr(CO)4Na(Et2O)(Bpp)1,5]n（III）。化合物 II 和 III 通过元素分析、核磁共振和红外光谱进行了表征。通过 X 射线衍射（CCDC 编号：2278024）确定了 II 的分子结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.