Prolonging the n-type conduction of thermoelectric carbon nanotubes exposed to warm air by mixing hydrated water into the adsorbed dopant layers composed of Li+-receptor molecules†

Shinichi Hata, Chika Nakagawa, Ayako Taketoshi, Toru Murayama, Tamao Ishida, Yukou Du, Yukihide Shiraishi and Naoki Toshima
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Abstract

Mixing hydrated water into the dopant layer prolongs the operational stability of n-type carbon nanotubes (CNTs). Supramolecular interactions with Li+ increase the water adsorption of the dopant layer, hinder atmospheric oxygen from entering the CNT structure, and extend the n-type lifetime at 373 K from 6 to 16 d.

Abstract Image

通过在由 Li+ 受体分子组成的吸附掺杂层中混入水合水,延长暴露在暖空气中的热电纳米碳管的 n 型传导时间†。
将水合水混合到掺杂剂层中可延长 n 型碳纳米管(CNT)的工作稳定性。与 Li+ 的超分子相互作用增加了掺杂层对水的吸附,阻碍了大气中的氧气进入 CNT 结构,并将 373 K 下的 n 型寿命从 6 d 延长到 16 d。
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